(((4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-yloxy)methyl)benzene

Base Information

Chemical Name:(((4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-yloxy)methyl)benzene
CAS No.:1391710-80-7
Molecular Formula:C₂₆H₄₄O₃
Molecular Weight:404.634
Hs Code.:

Synonyms:(((4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-yloxy)methyl)benzene

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Chemical Property of (((4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-yloxy)methyl)benzene

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Technology Process of (((4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-yloxy)methyl)benzene

There total 10 articles about (((4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-yloxy)methyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1391710-78-3
(4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-ol

: 100-39-0
benzyl bromide

: 1391710-80-7
(((4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-yloxy)methyl)benzene

Guidance literature:: (4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-ol; With sodium hydride; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

benzyl bromide; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1016/j.tetasy.2012.05.025

Reference yield:

: 1391710-68-1
methyl (R)-4-(methoxymethoxy)pentadecanoate

: 1391710-80-7
(((4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-yloxy)methyl)benzene

Guidance literature:: Multi-step reaction with 8 steps

1.1: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / -78 °C / Inert atmosphere

1.2: Saturated solution

2.1: D-Prolin / dimethyl sulfoxide / 0.5 h / 25 °C / Inert atmosphere

3.1: methanol; sodium tetrahydroborate / dimethyl sulfoxide / 0.33 h / 0 °C

4.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 12 h / 760.05 Torr

5.1: di(n-butyl)tin oxide; triethylamine / dichloromethane / 6 h / 20 °C / Inert atmosphere

6.1: potassium carbonate / methanol / 1 h / 0 °C

7.1: magnesium / tetrahydrofuran / Inert atmosphere

7.2: 12 h / -30 °C / Inert atmosphere

7.3: Saturated solution

8.1: sodium hydride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

8.2: 0 - 20 °C / Inert atmosphere

With methanol; sodium tetrahydroborate; palladium 10% on activated carbon; hydrogen; sodium hydride; diisobutylaluminium hydride; di(n-butyl)tin oxide; potassium carbonate; magnesium; triethylamine; D-Prolin; In tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; ethyl acetate; toluene;
DOI:10.1016/j.tetasy.2012.05.025

Reference yield:

: 1391710-69-2
(2S,4R)-4-(methoxymethoxy)pentadecane-1,2-diol

: 1391710-80-7
(((4R,6R)-6-(methoxymethoxy)heptadec-1-en-4-yloxy)methyl)benzene

Guidance literature:: Multi-step reaction with 4 steps

1.1: di(n-butyl)tin oxide; triethylamine / dichloromethane / 6 h / 20 °C / Inert atmosphere

2.1: potassium carbonate / methanol / 1 h / 0 °C

3.1: magnesium / tetrahydrofuran / Inert atmosphere

3.2: 12 h / -30 °C / Inert atmosphere

3.3: Saturated solution

4.1: sodium hydride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

4.2: 0 - 20 °C / Inert atmosphere

With sodium hydride; di(n-butyl)tin oxide; potassium carbonate; magnesium; triethylamine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/j.tetasy.2012.05.025