C₄₉H₆₀O₉

Base Information

Chemical Name:C₄₉H₆₀O₉
CAS No.:938455-50-6
Molecular Formula:C₄₉H₆₀O₉
Molecular Weight:793.01
Hs Code.:

C<sub>49</sub>H<sub>60</sub>O<sub>9</sub>

Synonyms:C₄₉H₆₀O₉

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Chemical Property of C₄₉H₆₀O₉

Chemical Property:

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Technology Process of C₄₉H₆₀O₉

There total 30 articles about C₄₉H₆₀O₉ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 938455-49-3
C₄₉H₆₀O₁₀

: 938455-50-6
C₄₉H₆₀O₉

Guidance literature:: With triethylsilane; trimethylsilyl trifluoromethanesulfonate; In acetonitrile; at -10 ℃; for 0.25h;
DOI:10.1016/j.tet.2007.02.039

Reference yield:

: 100-39-0
benzyl bromide

: 938455-50-6
C₄₉H₆₀O₉

Guidance literature:: Multi-step reaction with 17 steps

1.1: NaH / dimethylformamide / 1.5 h / 0 °C

1.2: Bu₄NI / dimethylformamide / 15 h / 20 °C

2.1: 3.95 g / p-TsOH*H₂O / methanol / 3 h / 40 - 70 °C

3.1: 2,6-lutidine / CH₂Cl₂ / 1.5 h / 20 °C

4.1: 4.77 g / CSA / CH₂Cl₂; methanol / 2 h / 0 °C

5.1: 94 percent / Et₃N; SO₃*pyridine / CH₂Cl₂; dimethylsulfoxide / 2.5 h / 20 °C / Parikh-Doering oxidation

6.1: t-BuLi; HMPA / tetrahydrofuran; pentane / 0.33 h / -78 °C

6.2: 95 percent / tetrahydrofuran; pentane / 1.5 h / -78 °C

7.1: 93 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 - 20 °C

8.1: 98 percent / methanol; tetrahydrofuran / 11 h / 20 °C

9.1: 93 percent / HF*pyridine; pyridine / tetrahydrofuran / 15 h / 20 °C

10.1: 87 percent / pyridinium p-toluenesulfonate / toluene / 3.5 h / 100 °C

11.1: 92 percent / DIBALH / toluene / 2 h / -78 °C

12.1: BH₃*THF / tetrahydrofuran / 3 h / 0 - 20 °C

12.2: 91 percent / aq. NaOH; H₂O₂ / tetrahydrofuran / 3.5 h / 20 °C

13.1: 5.13 g / 2,6-lutidine / CH₂Cl₂ / 1.5 h / 20 °C

14.1: DDQ; phosphate buffer / CH₂Cl₂ / 1 h / 0 °C / pH 7

15.1: tetra-n-propylammonium perruthenate; NMO; molecular sieves 4 Angstroem / CH₂Cl₂ / 6.08 h / 0 - 20 °C

16.1: 2.89 g / TBAF; acetic acid / tetrahydrofuran / 7.5 h / 20 °C

17.1: 83 percent / TMSOTf; Et₃SiH / acetonitrile / 0.25 h / -10 °C

With pyridine; 2,6-dimethylpyridine; triethylsilane; N,N,N,N,N,N-hexamethylphosphoric triamide; N-methyl-2-indolinone; phosphate buffer; tetrapropylammonium perruthennate; borane-THF; oxalyl dichloride; pyridine-SO₃ complex; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; tert.-butyl lithium; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; pyridine hydrogenfluoride; acetic acid; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; acetonitrile; pentane; 7.1: Swern oxidation;
DOI:10.1016/j.tet.2007.02.039

Reference yield:

: 938455-96-0
C₂₅H₃₂O₅

: 938455-50-6
C₄₉H₆₀O₉

Guidance literature:: Multi-step reaction with 17 steps

1.1: NaH / dimethylformamide / 1.5 h / 0 °C

1.2: Bu₄NI / dimethylformamide / 15 h / 20 °C

2.1: 3.95 g / p-TsOH*H₂O / methanol / 3 h / 40 - 70 °C

3.1: 2,6-lutidine / CH₂Cl₂ / 1.5 h / 20 °C

4.1: 4.77 g / CSA / CH₂Cl₂; methanol / 2 h / 0 °C

5.1: 94 percent / Et₃N; SO₃*pyridine / CH₂Cl₂; dimethylsulfoxide / 2.5 h / 20 °C / Parikh-Doering oxidation

6.1: t-BuLi; HMPA / tetrahydrofuran; pentane / 0.33 h / -78 °C

6.2: 95 percent / tetrahydrofuran; pentane / 1.5 h / -78 °C

7.1: 93 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 - 20 °C

8.1: 98 percent / methanol; tetrahydrofuran / 11 h / 20 °C

9.1: 93 percent / HF*pyridine; pyridine / tetrahydrofuran / 15 h / 20 °C

10.1: 87 percent / pyridinium p-toluenesulfonate / toluene / 3.5 h / 100 °C

11.1: 92 percent / DIBALH / toluene / 2 h / -78 °C

12.1: BH₃*THF / tetrahydrofuran / 3 h / 0 - 20 °C

12.2: 91 percent / aq. NaOH; H₂O₂ / tetrahydrofuran / 3.5 h / 20 °C

13.1: 5.13 g / 2,6-lutidine / CH₂Cl₂ / 1.5 h / 20 °C

14.1: DDQ; phosphate buffer / CH₂Cl₂ / 1 h / 0 °C / pH 7

15.1: tetra-n-propylammonium perruthenate; NMO; molecular sieves 4 Angstroem / CH₂Cl₂ / 6.08 h / 0 - 20 °C

16.1: 2.89 g / TBAF; acetic acid / tetrahydrofuran / 7.5 h / 20 °C

17.1: 83 percent / TMSOTf; Et₃SiH / acetonitrile / 0.25 h / -10 °C

With pyridine; 2,6-dimethylpyridine; triethylsilane; N,N,N,N,N,N-hexamethylphosphoric triamide; N-methyl-2-indolinone; phosphate buffer; tetrapropylammonium perruthennate; borane-THF; oxalyl dichloride; pyridine-SO₃ complex; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; tert.-butyl lithium; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; pyridine hydrogenfluoride; acetic acid; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; acetonitrile; pentane; 7.1: Swern oxidation;
DOI:10.1016/j.tet.2007.02.039