trans-carbonylchlorobis(phenyldi-t-butylphosphine)iridium(I)

Base Information

• Chemical Name: trans-carbonylchlorobis(phenyldi-t-butylphosphine)iridium(I)
• CAS No.: 32628-35-6
• Molecular Formula: C₂₉H₄₆ClIrOP₂
• Molecular Weight: 700.304
• Mol file: 32628-35-6.mol

Synonyms:trans-carbonylchlorobis(phenyldi-t-butylphosphine)iridium(I)

Chemical Property of trans-carbonylchlorobis(phenyldi-t-butylphosphine)iridium(I)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of trans-carbonylchlorobis(phenyldi-t-butylphosphine)iridium(I)

There total 3 articles about trans-carbonylchlorobis(phenyldi-t-butylphosphine)iridium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

carbon monoxide (201230-82-2) + [IrCl(H)(PtBu2C6H4-κ2P,C)(PtBu2Ph)] → trans-carbonylchlorobis(phenyldi-t-butylphosphine)iridium(I) (32628-35-6)

Guidance literature:

In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejic.201500363

Reference yield: 92.0%

hydrogen hexachloroiridate(IV) hydrate + tert-butyldiphenylphosphine (6002-34-2) → trans-carbonylchlorobis(phenyldi-t-butylphosphine)iridium(I) (32628-35-6)

Guidance literature:

In 2-methoxy-ethanol; refluxing soln. of H2IrCl6 for 5 min, addn. of phosphine (40°C), refluxing for 48 h; crystn.;

DOI:10.1039/DT9760002069

Reference yield:

iridium(III) chloride trihydrate + di(tertbutyl)phenylphosphine (32673-25-9) → trans-carbonylchlorobis(phenyldi-t-butylphosphine)iridium(I) (32628-35-6)

Guidance literature:

With carbon monoxide; In 2-methoxy-ethanol; CO was bubbled through a soln. of IrCl3*3H2O in 2-methoxyethanol, the mixt. was refluxed for 1 h, phosphine was added to the stirring hot soln., the mixt. was slowly cooled (N2 atm.);; recrystd. from toluene-methanol; elem. anal.;;

upstream raw materials:

di(tertbutyl)phenylphosphine

tert-butyldiphenylphosphine

carbon monoxide