Technology Process of C29H36N2O3S2
There total 5 articles about C29H36N2O3S2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Methyltriphenylphosphonium bromide;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 - 0 ℃;
for 0.666667h;
Inert atmosphere;
C28H34N2O4S2;
In
tetrahydrofuran;
at -78 - 20 ℃;
for 2h;
Inert atmosphere;
DOI:10.1021/ja408114u
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: diisobutylaluminium hydride / dichloromethane / 1 h / 0 °C / Inert atmosphere
2.1: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere
3.1: n-butyllithium / tetrahydrofuran; hexane / 0.67 h / -78 - 0 °C / Inert atmosphere
3.2: 2 h / -78 - 20 °C / Inert atmosphere
With
n-butyllithium; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane;
In
tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ja408114u
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: titanium(IV) tetraethanolate / tetrahydrofuran / 24 h / 20 °C / Inert atmosphere
2.1: lithium hexamethyldisilazane / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere
2.2: 2 h / -78 °C / Inert atmosphere
3.1: lithium hexamethyldisilazane / N,N-dimethyl-formamide / 0.67 h / -15 °C / Inert atmosphere
3.2: 2 h / -15 °C / Inert atmosphere
4.1: diisobutylaluminium hydride / dichloromethane / 1 h / 0 °C / Inert atmosphere
5.1: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere
6.1: n-butyllithium / tetrahydrofuran; hexane / 0.67 h / -78 - 0 °C / Inert atmosphere
6.2: 2 h / -78 - 20 °C / Inert atmosphere
With
titanium(IV) tetraethanolate; n-butyllithium; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; lithium hexamethyldisilazane;
In
tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja408114u
