(C₅H₅)(CO)Ru(P(C₆H₅)3)C(O)(C₆H₅)

Base Information

Chemical Name:(C₅H₅)(CO)Ru(P(C₆H₅)3)C(O)(C₆H₅)
CAS No.:117024-36-9
Molecular Formula:C₃₁H₂₅O₂PRu
Molecular Weight:561.582
Hs Code.:

(C<sub>5</sub>H<sub>5</sub>)(CO)Ru(P(C<sub>6</sub>H<sub>5</sub>)3)C(O)(C<sub>6</sub>H<sub>5</sub>)

Synonyms:(C₅H₅)(CO)Ru(P(C₆H₅)3)C(O)(C₆H₅)

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Chemical Property of (C₅H₅)(CO)Ru(P(C₆H₅)3)C(O)(C₆H₅)

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Technology Process of (C₅H₅)(CO)Ru(P(C₆H₅)3)C(O)(C₆H₅)

There total 1 articles about (C₅H₅)(CO)Ru(P(C₆H₅)3)C(O)(C₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 91482-99-4
(C₅H₅)(CO)2Ru(P(C₆H₅)3)⁽¹⁺⁾*PF₆^(1-)=(C₅H₅)(CO)2Ru(P(C₆H₅)3)PF₆

: 100-58-3
phenylmagnesium bromide

: 117024-36-9
(C₅H₅)(CO)Ru(P(C₆H₅)3)C(O)(C₆H₅)

Guidance literature:: With water; In tetrahydrofuran; under N2; CpRu(CO)2(PPh3)(1+)*PF6(1-) in THF stirred at -78°C; addn. of 2 equiv. C5H5MgBr ether soln.; allowed to warm slowly and addn. of some drops of water;; evapn.; chromd.(Al2O3, hexane/ethyl acetate); evapn.;
DOI:10.1021/om00103a016

Reference yield: 68.0%

: 117024-36-9
(C₅H₅)(CO)Ru(P(C₆H₅)3)C(O)(C₆H₅)

: 420-37-1
trimethoxonium tetrafluoroborate

: (C₅H₅)(CO)Ru(P(C₆H₅)3)CH(OCH₃)(C₆H₅)

Guidance literature:: With sodium tetrahydroborate; sodium methylate; In methanol; dichloromethane; Cp(CO)(PPh3)RuCOC6H5, 2-3 equiv. (CH3)3O(1+)BF4(1-) stirred (N2) in CH2Cl2 (24h); addn. of the resulting soln. of Cp(CO)(PPh3)Ru=C(OCH3)C6H5(1+) to soln. of 2 equiv. NaBH4 and 4equiv. NaOCH3 in CH3OH at -80°C; stirred 15 min; poured in aq. K2CO3; extn. (CH2Cl2); dried (K2CO3), concn.; chromd. (Al2O3, hexane/ethyl acetate); recrystn. hexane soln. gave crystals; isomer ratio ca. 5:1;
DOI:10.1021/om00103a016