(OC)4Mn(μ-SiPh2)(μ-H)Pt(PPh3)2

Base Information

• Chemical Name: (OC)4Mn(μ-SiPh2)(μ-H)Pt(PPh3)2
• CAS No.: 118398-34-8
• Molecular Formula: C₅₂H₄₁MnO₄P₂PtSi
• Molecular Weight: 1069.95
• Mol file: 118398-34-8.mol

Synonyms:(OC)4Mn(μ-SiPh2)(μ-H)Pt(PPh3)2

Chemical Property of (OC)4Mn(μ-SiPh2)(μ-H)Pt(PPh3)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (OC)4Mn(μ-SiPh2)(μ-H)Pt(PPh3)2

There total 2 articles about (OC)4Mn(μ-SiPh2)(μ-H)Pt(PPh3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) + Mn(CO)5Si(C6H5)2H (118398-32-6) → (OC)4Mn(μ-SiPh2)(μ-H)Pt(PPh3)2 (118398-34-8)

Guidance literature:

In toluene; stirring educts in toluene at room temp. for 1-2 h under dry and oxygen-free conditions; concn., pptn., filtration, drying ; elem. anal.;

Reference yield: 66.0%

tetrakis(triphenylphosphine)platinum (14221-02-4) + Mn(CO)5Si(C6H5)2H (118398-32-6) → (OC)4Mn(μ-SiPh2)(μ-H)Pt(PPh3)2 (118398-34-8)

Guidance literature:

In toluene; stirring educts in toluene at room temp. for 1-2 h under dry and oxygen-free conditions; concn., pptn., filtration, drying ; elem. anal.;

Reference yield: 68.0%

(OC)4Mn(μ-SiPh2)(μ-H)Pt(PPh3)2 (118398-34-8) + triethylphosphine (554-70-1) → (OC)4Mn(μ-SiPh2)(μ-H)Pt(PEt3)2 (118398-36-0)

Guidance literature:

In hexane; addn. of PEt3 to suspension of PPh3-complex, stirring at room temp. for 5 h (dry and oxygen-free conditions); decanting, washing of remaining solid with hexane, drying ; elem. anal.;

upstream raw materials:

ethylenebis(triphenylphosphine)platinum⁽⁰⁾

Mn(CO)5Si(C₆H₅)2H

tetrakis(triphenylphosphine)platinum

Downstream raw materials:

(OC)4Mn(μ-SiPh2)(μ-H)Pt(PEt3)2

tetracarbonylhydrido(triphenylphosphine)manganese

(OC)4Mn(μ-PPh2)(μ-H)PtPh(PPh3)

dimethoxy(diphenyl)silane

Refernces