(2R,3R,5R)-5-Acetyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-cyclohexanone

Base Information

Chemical Name:(2R,3R,5R)-5-Acetyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-cyclohexanone
CAS No.:191410-01-2
Molecular Formula:C₁₅H₂₈O₃Si
Molecular Weight:284.471
Hs Code.:

Synonyms:(2R,3R,5R)-5-Acetyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-cyclohexanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3R,5R)-5-Acetyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-cyclohexanone

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Technology Process of (2R,3R,5R)-5-Acetyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-cyclohexanone

There total 4 articles about (2R,3R,5R)-5-Acetyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-cyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 191410-00-1
(2R,3R,5R)-3-tert-butyldimethylsilyloxy-2-methyl-5-(1-methylethenyl)cyclohexanone

: 191410-01-2
(2R,3R,5R)-5-Acetyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-cyclohexanone

Guidance literature:: With osmium(VIII) oxide; potassium metaperiodate; In tetrahydrofuran; for 12h;
DOI:10.1016/S0957-4166(97)00170-5

Reference yield:

: 36616-60-1
(1R,4R,6R)-4-isopropenyl-1-methyl-7-oxabicyclo[4.1.0]heptan-2-one

: 191410-01-2
(2R,3R,5R)-5-Acetyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-cyclohexanone

Guidance literature:: Multi-step reaction with 3 steps

1: 63 percent / Ph₂Se₂, NaBH₄ / ethanol; acetic acid / 0.25 h / 0 °C

2: 89 percent / 2,6-lutidine / CH₂Cl₂ / 0.33 h / 0 °C

3: KIO₄, OsO₄ / tetrahydrofuran; H₂O / 12 h

With 2,6-dimethylpyridine; sodium tetrahydroborate; osmium(VIII) oxide; potassium metaperiodate; diphenyl diselenide; In tetrahydrofuran; ethanol; dichloromethane; water; acetic acid;

Reference yield:

: 6485-40-1,2244-16-8
(R)-Carvone

: 191410-01-2
(2R,3R,5R)-5-Acetyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-cyclohexanone

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / H₂O₂, NaOH / methanol / 3 h / -10 °C

2: 63 percent / Ph₂Se₂, NaBH₄ / ethanol; acetic acid / 0.25 h / 0 °C

3: 89 percent / 2,6-lutidine / CH₂Cl₂ / 0.33 h / 0 °C

4: KIO₄, OsO₄ / tetrahydrofuran; H₂O / 12 h

With 2,6-dimethylpyridine; sodium hydroxide; sodium tetrahydroborate; osmium(VIII) oxide; potassium metaperiodate; diphenyl diselenide; dihydrogen peroxide; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; acetic acid;