4-methyl-N-(4-methyl-penta-2,3-dienyl)-N-(4-methyl-penta-2,4-dienyl)-benzenesulfonamide

Base Information

• Chemical Name: 4-methyl-N-(4-methyl-penta-2,3-dienyl)-N-(4-methyl-penta-2,4-dienyl)-benzenesulfonamide
• CAS No.: 892394-57-9
• Molecular Formula: C₁₉H₂₅NO₂S
• Molecular Weight: 331.479
• Mol file: 892394-57-9.mol

Synonyms:4-methyl-N-(4-methyl-penta-2,3-dienyl)-N-(4-methyl-penta-2,4-dienyl)-benzenesulfonamide

Chemical Property of 4-methyl-N-(4-methyl-penta-2,3-dienyl)-N-(4-methyl-penta-2,4-dienyl)-benzenesulfonamide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 4-methyl-N-(4-methyl-penta-2,3-dienyl)-N-(4-methyl-penta-2,4-dienyl)-benzenesulfonamide

There total 1 articles about 4-methyl-N-(4-methyl-penta-2,3-dienyl)-N-(4-methyl-penta-2,4-dienyl)-benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

(2E)-4-methylpenta-2,4-dien-1-ol (67065-89-8) + 4-methyl-N-(4-methylpenta-2,3-dienyl)benzenesulfonamide → 4-methyl-N-(4-methyl-penta-2,3-dienyl)-N-(4-methyl-penta-2,4-dienyl)-benzenesulfonamide (892394-57-9)

Guidance literature:

With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 24h;

DOI:10.1002/anie.200600300

Reference yield: 99.0%

4-methyl-N-(4-methyl-penta-2,3-dienyl)-N-(4-methyl-penta-2,4-dienyl)-benzenesulfonamide (892394-57-9) + carbon monoxide (201230-82-2) → 4-isopropenyl-6-isopropylidene-2-(toluene-4-sulfonyl)-hexahydro-cyclopenta[c]pyrrol-5-one

Guidance literature:

With di(rhodium)tetracarbonyl dichloride; In 1,2-dichloro-ethane; at 20 ℃; for 7h; under 760 Torr;

DOI:10.1002/anie.200600300

upstream raw materials:

(2E)-4-methylpenta-2,4-dien-1-ol