4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one

Base Information

Chemical Name:4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one
CAS No.:121402-05-9
Molecular Formula:C₃₁H₅₂O₄Si
Molecular Weight:516.837
Hs Code.:

Synonyms:4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one

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Chemical Property of 4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one

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Technology Process of 4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one

There total 12 articles about 4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.8%

: 121402-04-8
C₃₄H₅₄O₇Si

: 121402-05-9
4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one

Guidance literature:: With sodium tetrahydroborate; In 1,2-dimethoxyethane; for 4h; Ambient temperature;
DOI:10.1016/S0040-4039(00)87892-2

Reference yield:

: 121401-97-6
(S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5,5-bis-ethylsulfanyl-pentan-2-one

: 121402-05-9
4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one

Guidance literature:: Multi-step reaction with 5 steps

1: 1,2-dimethoxy-ethane / 60 h / -20 °C

2: 1.) lithium diisopropylamide / 1.) THF, -78 deg C

3: 76 percent / ammonium formate / Pd/C / methanol / 8 h / Ambient temperature

4: Et₃N / tetrahydrofuran / 1 h / -10 °C

5: 67.8 percent / NaBH₄ / 1,2-dimethoxy-ethane / 4 h / Ambient temperature

With sodium tetrahydroborate; ammonium formate; triethylamine; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; methanol; 1,2-dimethoxyethane;
DOI:10.1016/S0040-4039(00)87892-2

Reference yield:

: 121401-98-7,121402-06-0
(E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-(tert-butyl-dimethyl-silanyloxymethyl)-6,6-bis-ethylsulfanyl-hex-2-enoic acid ethyl ester

: 121402-05-9
4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) lithium diisopropylamide / 1.) THF, -78 deg C

2: 76 percent / ammonium formate / Pd/C / methanol / 8 h / Ambient temperature

3: Et₃N / tetrahydrofuran / 1 h / -10 °C

4: 67.8 percent / NaBH₄ / 1,2-dimethoxy-ethane / 4 h / Ambient temperature

With sodium tetrahydroborate; ammonium formate; triethylamine; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; methanol; 1,2-dimethoxyethane;
DOI:10.1016/S0040-4039(00)87892-2