(NZ)-N-[1-(4-aminophenyl)ethylidene]hydroxylamine

Base Information

• Chemical Name: (NZ)-N-[1-(4-aminophenyl)ethylidene]hydroxylamine
• CAS No.: 38063-81-9
• Molecular Formula: C8H10N2O
• Molecular Weight: 150.18
• Hs Code.: 2928000090
• NSC Number: 77944
• Nikkaji Number: J918.921A,J89.195I
• Mol file: 38063-81-9.mol

Synonyms:(NZ)-N-[1-(4-aminophenyl)ethylidene]hydroxylamine;1-(4-aminophenyl)ethanone oxime;38063-81-9;NSC77944;4'-Aminoacetophenone (E)-oxime;HMS1577F03;NSC-77944

Chemical Property of (NZ)-N-[1-(4-aminophenyl)ethylidene]hydroxylamine

Chemical Property:

• Vapor Pressure: 0.000107mmHg at 25°C
• Melting Point: 153oC
• Boiling Point: 323.5°C at 760 mmHg
• Flash Point: 149.5°C
• PSA: 58.61000
• Density: 1.14g/cm³
• LogP: 2.04820
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 150.079312947
• Heavy Atom Count: 11
• Complexity: 148

Purity/Quality:

97% ^*data from raw suppliers

4-Aminoacetophenone oxime ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=NO)C1=CC=C(C=C1)N
• Isomeric SMILES: C/C(=N/O)/C1=CC=C(C=C1)N

Technology Process of (NZ)-N-[1-(4-aminophenyl)ethylidene]hydroxylamine

There total 6 articles about (NZ)-N-[1-(4-aminophenyl)ethylidene]hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

p-nitroacetophenone oxime (10342-64-0) → p-aminoacetophenone oxime (38063-81-9)

Guidance literature:

With borane-ammonia complex; copper(II) oxide; In methanol; at 50 ℃; for 0.333333h; chemoselective reaction;

DOI:10.1002/cctc.201902391

Reference yield: 85.0%

→ p-aminoacetophenone oxime (38063-81-9)

Guidance literature:

With ammonia borane; In methanol; at 20 ℃;

Reference yield: 84.0%

p-nitroacetophenone oxime (10342-64-0) → p-aminoacetophenone oxime (38063-81-9) + p-aminobenzophenone (99-92-3)

Guidance literature:

With sodium tetrahydroborate; tin(ll) chloride; In ethanol; at 60 ℃; for 0.5h;

upstream raw materials:

p-aminobenzophenone

p-nitroacetophenone oxime

Downstream raw materials:

1-(4-amino-phenyl)-ethanone O-(2-morpholin-4-yl-ethyl)-oxime

4-{[1-(4-amino-phenyl)-ethylideneaminooxy]-acetyl}-morpholine

1-vinyl-2-(4-aminophenyl)pyrrole

2-(4-aminophenyl)pyrrole