Technology Process of 2-(tert-butylthio)phenyldiphenylarsine
There total 2 articles about 2-(tert-butylthio)phenyldiphenylarsine which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
tert-butyl phenyl sulfide;
With
n-butyllithium; N,N,N,N,-tetramethylethylenediamine;
In
hexane;
at 10 - 20 ℃;
for 21h;
Inert atmosphere;
Schlenk technique;
chlorodiphenylarsine;
In
hexane;
for 2h;
Inert atmosphere;
Schlenk technique;
With
sodium hydroxide;
In
hexane; water;
Inert atmosphere;
Schlenk technique;
DOI:10.1071/CH13262
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: iron(III) chloride; trichlorophosphate
2.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / hexane / 21 h / 10 - 20 °C / Inert atmosphere; Schlenk technique
2.2: 2 h / Inert atmosphere; Schlenk technique
2.3: Inert atmosphere; Schlenk technique
With
iron(III) chloride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; trichlorophosphate;
In
hexane;
DOI:10.1071/CH13262
- Guidance literature:
-
2-(tert-butylthio)phenyldiphenylarsine;
With
n-butyllithium; N,N,N,N,-tetramethylethylenediamine;
In
hexane;
at 20 ℃;
for 20.75h;
Inert atmosphere;
Schlenk technique;
Cooling with ice;
chlorodiphenylarsine;
In
hexane;
Inert atmosphere;
Schlenk technique;
Cooling with ice;
With
sodium hydroxide;
In
hexane; water;
Inert atmosphere;
Schlenk technique;
DOI:10.1071/CH13262
