4-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methyl-3-vinyl-cyclohex-2-enone

Base Information

Chemical Name:4-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methyl-3-vinyl-cyclohex-2-enone
CAS No.:263545-54-6
Molecular Formula:C₁₈H₃₂O₂Si
Molecular Weight:308.536
Hs Code.:

4-[3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-propyl]-4-methyl-3-vinyl-cyclohex-2-enone

Synonyms:4-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methyl-3-vinyl-cyclohex-2-enone

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Chemical Property of 4-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methyl-3-vinyl-cyclohex-2-enone

Chemical Property:

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Technology Process of 4-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methyl-3-vinyl-cyclohex-2-enone

There total 4 articles about 4-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methyl-3-vinyl-cyclohex-2-enone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1826-67-1
vinyl magnesium bromide

: 263545-53-5
6-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-methoxymethoxy-6-methyl-cyclohex-2-enone

: 263545-54-6
4-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methyl-3-vinyl-cyclohex-2-enone

Guidance literature:: In tetrahydrofuran; at 0 ℃;
DOI:10.1016/S0040-4039(99)02175-9

Reference yield:

: 78878-05-4
1-iodo-3-(tert-butyldimethylsilyloxy)propane

: 263545-54-6
4-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methyl-3-vinyl-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / LDA / hexamethylphosphoric acid triamide; tetrahydrofuran / -78 - 20 °C

2: 96 percent / LDA / tetrahydrofuran

3: 92 percent / tetrahydrofuran / 0 °C

With lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; 1: Alkylation / 2: Metallation / 3: Grignard reaction;
DOI:10.1016/S0040-4039(99)02175-9

Reference yield:

: 111596-58-8
3-(methoxymethoxy)-2-cyclohexenone

: 263545-54-6
4-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methyl-3-vinyl-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / LDA / hexamethylphosphoric acid triamide; tetrahydrofuran / -78 - 20 °C

2: 96 percent / LDA / tetrahydrofuran

3: 92 percent / tetrahydrofuran / 0 °C

With lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; 1: Alkylation / 2: Metallation / 3: Grignard reaction;
DOI:10.1016/S0040-4039(99)02175-9