2-Anthraquinonesulfonic acid

Base Information

• Chemical Name: 2-Anthraquinonesulfonic acid
• CAS No.: 84-48-0
• Molecular Formula: C14H8 O5 S
• Molecular Weight: 288.281
• Hs Code.: 2914399090
• European Community (EC) Number: 201-532-8
• NSC Number: 229389
• UNII: C0S001C4YJ
• DSSTox Substance ID: DTXSID6045030
• Nikkaji Number: J79.430I
• Wikidata: Q27275022
• ChEMBL ID: CHEMBL3305895
• Mol file: 84-48-0.mol

Synonyms:9,10-anthraquinone-2-sulfonate;anthraquinone sulfonate;anthraquinone sulfonate, potassium salt;anthraquinone sulfonate, sodium salt;anthraquinone-2-sulfonic acid

Chemical Property of 2-Anthraquinonesulfonic acid

Chemical Property:

• PKA: pK1: 0.38 (25°C)
• PSA: 96.89000
• Density: 1.585g/cm³
• LogP: 2.78950
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 1
• Exact Mass: 288.00924453
• Heavy Atom Count: 20
• Complexity: 532

Purity/Quality:

97% ^*data from raw suppliers

2-ANTHRAQUINONESULFONIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(=O)C3=C(C2=O)C=C(C=C3)S(=O)(=O)O

Technology Process of 2-Anthraquinonesulfonic acid

There total 42 articles about 2-Anthraquinonesulfonic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sulfuric acid (7664-93-9) + 9,10-phenanthrenequinone (84-65-1) → 1-anthraquinonesulfonic acid (82-49-5) + 2-sulfo-anthraquinone (84-48-0)

Guidance literature:

Reference yield:

sodium 1-amino-4-bromoanthraquinone-2-sulfonate (6258-06-6) → 2-sulfo-anthraquinone (84-48-0)

Guidance literature:

sodium 1-amino-4-bromoanthraquinone-2-sulfonate; With sulfuric acid; water; sodium nitrite; In water; at 20 - 40 ℃; for 1.33333h;

With ethanol; zinc; In water; at 0 - 110 ℃;

DOI:10.1016/j.tetlet.2012.09.011

Reference yield:

9,10-phenanthrenequinone (84-65-1) → 2-sulfo-anthraquinone (84-48-0)

Guidance literature:

With sulfuric acid; sulfur trioxide; at 160 ℃;

upstream raw materials:

2-Benzoylbenzoic acid

9,10-phenanthrenequinone

9,10-Anthrachinon-2-sulfonsaeure-Radikalanion

1-(5-Iodo-4-nitro-imidazol-1-yl)-3-methoxy-propan-2-ol

Downstream raw materials:

2-hydroxy-9,10-anthraquinone

1,2-dihydroxy-9,10-anthracenedione

2-chloroanthracene-9,10-dione

anthracene-2-sulfonic acid

Refernces

2-C-CARBOXYALDOSES AND ALDONIC ACIDS FROM CELLOBIOSE, MALTOSE, AND 4-O-METHYL-D-GLUCOSE WITH 2-ANTHRAQUINONESULFONIC ACID

10.1016/S0008-6215(00)90462-2

The research details an investigation into the oxidation of cellobiose, maltose, and 4-O-methyl-D-glucose using 2-anthraquinonesulfonic acid (AMS) in sodium hydroxide. The purpose of the study was to gain insights into the reactions of aldoses, specifically aldos-2-uloses, by subjecting these 4-O-substituted aldoses to oxidation conditions similar to those used for D-glucose. The research concluded that the oxidation products included erythronic, arabinonic, ribonic, gluconic, and mannonic acids, as well as 2-C-carboxypentoses, which were identified as a new type of product in the reaction mixture. The study also found that the nonsubstituted products of the reducing D-glucose unit consisted of formic, glycolic, 2-deoxytetronic, and 3-deoxypentonic acids, along with 2-C-carboxy-3-deoxypentoses. The chemicals used in the process included 2-anthraquinonesulfonic acid as the oxidizing agent, sodium hydroxide to maintain the reaction conditions, and various sugars as substrates for the oxidation reactions.