Benzoic acid (1R,3S,4S,6R)-6-benzyloxy-3-hexyl-4-hydroxy-1-methyl-2-oxo-heptadecyl ester

Base Information

Chemical Name:Benzoic acid (1R,3S,4S,6R)-6-benzyloxy-3-hexyl-4-hydroxy-1-methyl-2-oxo-heptadecyl ester
CAS No.:220583-64-2
Molecular Formula:C₃₈H₅₈O₅
Molecular Weight:594.876
Hs Code.:

Synonyms:Benzoic acid (1R,3S,4S,6R)-6-benzyloxy-3-hexyl-4-hydroxy-1-methyl-2-oxo-heptadecyl ester

Suppliers and Price of Benzoic acid (1R,3S,4S,6R)-6-benzyloxy-3-hexyl-4-hydroxy-1-methyl-2-oxo-heptadecyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzoic acid (1R,3S,4S,6R)-6-benzyloxy-3-hexyl-4-hydroxy-1-methyl-2-oxo-heptadecyl ester

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Benzoic acid (1R,3S,4S,6R)-6-benzyloxy-3-hexyl-4-hydroxy-1-methyl-2-oxo-heptadecyl ester

There total 3 articles about Benzoic acid (1R,3S,4S,6R)-6-benzyloxy-3-hexyl-4-hydroxy-1-methyl-2-oxo-heptadecyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13125-66-1
n-heptylmagnesium bromide

: 220583-64-2
Benzoic acid (1R,3S,4S,6R)-6-benzyloxy-3-hexyl-4-hydroxy-1-methyl-2-oxo-heptadecyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) MeONHMe*HCl, i-PrMgCl / 1.) THF, -20 deg C to 0 deg C, 1,5 h, 2.) THF, 0 deg C to 20 deg C, 4 h

2: i-Pr₂NEt, DMAP / 72 h

3: 1.) c-Hex₂BCl, Me₂NEt 3.) H₂O₂, NaOH / 1.) Et₂O, 0 deg C, 2 h, 2.) - 78 deg C, 4 h, 3.) MeOH, 0 deg C, 2 h

With dmap; sodium hydroxide; N,N-dimethyl-ethanamine; dicyclohexylboron chloride; dihydrogen peroxide; isopropylmagnesium chloride; N,O-dimethylhydroxylamine*hydrochloride; N-ethyl-N,N-diisopropylamine;
DOI:10.1016/S0040-4039(98)02321-1

Reference yield:

: 383416-55-5
(R)-2-Hydroxy-decan-3-one

: 220583-64-2
Benzoic acid (1R,3S,4S,6R)-6-benzyloxy-3-hexyl-4-hydroxy-1-methyl-2-oxo-heptadecyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: i-Pr₂NEt, DMAP / 72 h

2: 1.) c-Hex₂BCl, Me₂NEt 3.) H₂O₂, NaOH / 1.) Et₂O, 0 deg C, 2 h, 2.) - 78 deg C, 4 h, 3.) MeOH, 0 deg C, 2 h

With dmap; sodium hydroxide; N,N-dimethyl-ethanamine; dicyclohexylboron chloride; dihydrogen peroxide; N-ethyl-N,N-diisopropylamine;
DOI:10.1016/S0040-4039(98)02321-1

Reference yield:

: 112763-97-0
(R)-3-phenylmethyloxy-tetradecanal

: 220583-65-3
(R)-2-(benzoyloxy)decan-2-one

: 220583-64-2
Benzoic acid (1R,3S,4S,6R)-6-benzyloxy-3-hexyl-4-hydroxy-1-methyl-2-oxo-heptadecyl ester

Guidance literature:: With sodium hydroxide; N,N-dimethyl-ethanamine; dicyclohexylboron chloride; dihydrogen peroxide; Yield given; Multistep reaction; 1.) Et₂O, 0 deg C, 2 h, 2.) - 78 deg C, 4 h, 3.) MeOH, 0 deg C, 2 h;
DOI:10.1016/S0040-4039(98)02321-1