triphenylsilylzinc chloride

Base Information

• Chemical Name: triphenylsilylzinc chloride
• CAS No.: 1346656-94-7
• Molecular Formula: C₁₈H₁₅ClSiZn
• Molecular Weight: 360.246
• Mol file: 1346656-94-7.mol

Synonyms:triphenylsilylzinc chloride

Chemical Property of triphenylsilylzinc chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triphenylsilylzinc chloride

There total 1 articles about triphenylsilylzinc chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Triphenylsilyl chloride (76-86-8) + zinc(II) chloride (7646-85-7,24359-56-6) → triphenylsilylzinc chloride (1346656-94-7)

Guidance literature:

Triphenylsilyl chloride; With lithium; In tetrahydrofuran; at 0 ℃; for 14h; Inert atmosphere; Sonication;

zinc(II) chloride; In tetrahydrofuran; at 0 ℃; for 0.5h; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.6b03465

Reference yield: 91.0%

triphenylsilylzinc chloride (1346656-94-7) + (2E)-3-phenyl-2-propen-1-ol (4407-36-7) → cinnamyltriphenylsilane

Guidance literature:

(2E)-3-phenyl-2-propen-1-ol; With dichlorobis(trimethylphosphine)nickel; methylzinc chloride; In tetrahydrofuran; at 20 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

triphenylsilylzinc chloride; In tetrahydrofuran; at 20 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

In toluene; at 20 ℃; for 24h; regioselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.orglett.9b02946

Reference yield: 83.0%

S-phenyl 3-(4-methoxyphenyl)propanethioate (1346656-92-5) + triphenylsilylzinc chloride (1346656-94-7) → 3-(4-methoxyphenyl)-1-(triphenylsilyl)propan-1-one (1346656-96-9)

Guidance literature:

With bis(dibenzylideneacetone)-palladium⁽⁰⁾; tricyclohexylphosphine; In tetrahydrofuran; diethyl ether; at 20 ℃;

DOI:10.1246/cl.2011.959

upstream raw materials:

Triphenylsilyl chloride

zinc(II) chloride

Downstream raw materials:

3-(4-methoxyphenyl)-1-(triphenylsilyl)propan-1-one

[1,1'-biphenyl]-4-yltriphenylsilane

4,4'-Dimethoxybiphenyl

(4-methoxyphenyl)triphenylsilane

Refernces