Technology Process of methyl (Z)-10-(phenylsulfinyloxy)-dec-2-en-8-ynoate
There total 5 articles about methyl (Z)-10-(phenylsulfinyloxy)-dec-2-en-8-ynoate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
trimethyl phosphonoacetate;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at 0 ℃;
for 0.5h;
C14H16O3S;
In
tetrahydrofuran; hexane;
for 0.5h;
Further stages.;
DOI:10.1021/ol0709329
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: 673 mg / ethyldiisopropylamine / tetrahydrofuran / 1 h / -78 °C
2.1: 418 mg / pyridinium p-toluenesulfonate / methanol / 4 h / 20 °C
3.1: 150 mg / 2-iodoxybenzoic acid / ethyl acetate / 1 h / 80 °C
4.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / 0 °C
4.2: 21 percent / tetrahydrofuran; hexane / 0.5 h
With
n-butyllithium; pyridinium p-toluenesulfonate; N-ethyl-N,N-diisopropylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
tetrahydrofuran; methanol; hexane; ethyl acetate;
DOI:10.1021/ol0709329
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 418 mg / pyridinium p-toluenesulfonate / methanol / 4 h / 20 °C
2.1: 150 mg / 2-iodoxybenzoic acid / ethyl acetate / 1 h / 80 °C
3.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / 0 °C
3.2: 21 percent / tetrahydrofuran; hexane / 0.5 h
With
n-butyllithium; pyridinium p-toluenesulfonate; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
In
tetrahydrofuran; methanol; hexane; ethyl acetate;
DOI:10.1021/ol0709329
