C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃⁽¹⁺⁾*PF₆^(1-)=C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃PF₆

Base Information

• Chemical Name: C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃⁽¹⁺⁾*PF₆^(1-)=C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃PF₆
• CAS No.: 85565-46-4
• Molecular Formula: C₂₁H₃₂MoNO₂*F₆P
• Molecular Weight: 571.395

Synonyms:C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃⁽¹⁺⁾*PF₆^(1-)=C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃PF₆

Chemical Property of C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃⁽¹⁺⁾*PF₆^(1-)=C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃PF₆

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Technology Process of C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃⁽¹⁺⁾*PF₆^(1-)=C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃PF₆

There total 1 articles about C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃⁽¹⁺⁾*PF₆^(1-)=C₅H₄(C₁₀H₁₉)Mo(CO)(NO)CH₃CHCHCHCH₃PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

nitrosyl hexafluorophosphate (16921-91-8) + C5H4(C10H19)Mo(CO)2CH3CHCHCHCH3 (85565-44-2) → C5H4(C10H19)Mo(CO)(NO)CH3CHCHCHCH3(1+)*PF6(1-)=C5H4(C10H19)Mo(CO)(NO)CH3CHCHCHCH3PF6 (85565-46-4)

Guidance literature:

In acetonitrile; byproducts: CO; Mo complex dissolving in MeCN at 0.degrtee.C under N2, nitrosonium saltadding to yield a dark-brown color and CO evolution; after 5 min at 0°C mixt. adding dropwise to cold ether, ppt. sepg. off by centrifugation; purified by recrystn. from CH2Cl2-pentane; identified by elem. anal., IR and NMR spectra;

DOI:10.1021/ja00350a026

Reference yield: 60.0%

C5H4(C10H19)Mo(CO)(NO)CH3CHCHCHCH3(1+)*PF6(1-)=C5H4(C10H19)Mo(CO)(NO)CH3CHCHCHCH3PF6 (85565-46-4) + sodium tetraphenyl borate (143-66-8) → C5H4(C10H19)Mo(CO)(NO)CH3CHCHCHCH3(1+)*B(C6H5)4(1-)=C5H4(C10H19)Mo(CO)(NO)CH3CHCHCHCH3B(C6H5)4

Guidance literature:

In acetone; Mo complex dissolving in acetone under N2, NaBPh4 adding, stirring for 30 min, the solvent removing, extg. with CH2Cl2, evapg.; a mixt. of exo and endo isomers (2:1) was obtained; purified by recrystn. from CH2Cl2-pentane; identified by elem. anal., IR and NMR spectra;

DOI:10.1021/ja00350a026

Reference yield:

C5H4(C10H19)Mo(CO)(NO)CH3CHCHCHCH3(1+)*PF6(1-)=C5H4(C10H19)Mo(CO)(NO)CH3CHCHCHCH3PF6 (85565-46-4) + 1-(2-methylprop-1-en-1-yl)pyrrolidine (2403-57-8) → C5H4(C10H19)Mo(CO)(NO)CH3CHCHCH(CH3)C(CH3)2CHO + C5H4(C10H19)Mo(CO)(NO)CH3CHCHCH(CH3)C(CH3)2CHO

Guidance literature:

In acetonitrile; Mo complex dissolving in MeCN at 0°C under N2, organic reagent adding, chromg. on acidic alumina, evapg.; a mixt. of (R,R)- and (S,S)-isomers (32:48) was obtained, yield 80%; identified by NMR spectrum;

DOI:10.1021/ja00350a026

upstream raw materials:

nitrosyl hexafluorophosphate

C₅H₄(C₁₀H₁₉)Mo(CO)2CH₃CHCHCHCH₃

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