(κP,κC,κN-2-(i-Pr2PO)-6-(CH2N(benzyl)(allyl))C6H3)NiBr

Base Information

• Chemical Name: (κP,κC,κN-2-(i-Pr2PO)-6-(CH2N(benzyl)(allyl))C6H3)NiBr
• CAS No.: 1233486-88-8
• Molecular Formula: C₂₃H₃₁BrNNiOP
• Molecular Weight: 507.073
• Mol file: 1233486-88-8.mol

Synonyms:(κP,κC,κN-2-(i-Pr2PO)-6-(CH2N(benzyl)(allyl))C6H3)NiBr

Chemical Property of (κP,κC,κN-2-(i-Pr2PO)-6-(CH2N(benzyl)(allyl))C6H3)NiBr

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (κP,κC,κN-2-(i-Pr2PO)-6-(CH2N(benzyl)(allyl))C6H3)NiBr

There total 1 articles about (κP,κC,κN-2-(i-Pr2PO)-6-(CH2N(benzyl)(allyl))C6H3)NiBr which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

(κP,κC,κN-2,6-(i-Pr2PO)-C6H3-(N-(benzylamino)methyl))NiBr (1233486-86-6) + allyl bromide (106-95-6) → (κP,κC,κN-2-(i-Pr2PO)-6-(CH2N(benzyl)(allyl))C6H3)NiBr (1233486-88-8)

Guidance literature:

With MeLi; In tetrahydrofuran; hexane; byproducts: LiBr; under N2; soln. of MeLi in diethoxymethane added at -78°C to stirred soln. of Ni complex in dry degassed hexane-THF; stirred for 30 min; CH2CHCH2Br added; stirred at -78°C for 1 h and at room temp. overnight; isolated by flash chromy. (SiO2, benzene); elem. anal.;

DOI:10.1021/ic100914x

upstream raw materials:

(κP,κC,κN-2,6-(i-Pr2PO)-C6H3-(N-(benzylamino)methyl))NiBr

allyl bromide