(κP,κC,κN-2,6-(i-Pr2PO)-C6H3-(N-(benzylamino)methyl))NiBr

Base Information

Chemical Name:(κP,κC,κN-2,6-(i-Pr2PO)-C6H3-(N-(benzylamino)methyl))NiBr
CAS No.:1233486-86-6
Molecular Formula:C₂₀H₂₇BrNNiOP
Molecular Weight:467.008
Hs Code.:

Synonyms:(κP,κC,κN-2,6-(i-Pr2PO)-C6H3-(N-(benzylamino)methyl))NiBr

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Chemical Property of (κP,κC,κN-2,6-(i-Pr2PO)-C6H3-(N-(benzylamino)methyl))NiBr

Chemical Property:

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Technology Process of (κP,κC,κN-2,6-(i-Pr2PO)-C6H3-(N-(benzylamino)methyl))NiBr

There total 3 articles about (κP,κC,κN-2,6-(i-Pr2PO)-C6H3-(N-(benzylamino)methyl))NiBr which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 1233486-94-6
3-((N-benzylamino)methyl)diisopropylphosphinitobenzene

: Br₂Ni*(x)C₂H₃N

: 1233486-86-6
(κP,κC,κN-2,6-(i-Pr2PO)-C6H3-(N-(benzylamino)methyl))NiBr

Guidance literature:: With Et₃N; In toluene; benzene; under N2; soln. of ligand in benzene slowly added to stirred suspn. of Ni compd. and Et3N in toluene at room temp.; heated at 60°C for 3 h; washed with H2O; evapd. to dryness; purified by chromy. (silica gel, hexane, CH2Cl2-hexane 1:1); elem. anal.;
DOI:10.1021/ic100914x

Reference yield:

: 128-08-5
N-Bromosuccinimide

: 1233486-92-4
[κP,κC,κN,μN-(2,6-(i-Pr2POC6H3CH2NCH2Ph)Ni]2

: 1233486-86-6
[κP,κC,κN-(2,6-(i-Pr2POC6H3CH2NHCH2Ph)NiBr]

: 1269490-22-3
[κP,κC,κN-(2,6-(i-Pr2POC6H3CH=NCH2Ph)NiBr]

Guidance literature:: In dichloromethane; byproducts: succinimide, 3-(benzyliminomethyl)diisopropylphosphinitobenzene; under N2, Schlenk technique; N-bromosuccinimide (1 equiv.) added to soln. of Ni complex in CH2Cl2; NMR monitoring;
DOI:10.1021/ic1025894

Reference yield:

: Ni⁽²⁺⁾*Li⁽¹⁺⁾*Br^(1-)*C₆H₃(CH₂NCH₂C₆H₅)OP(CH(CH₃)2)2^(2-)=(C₆H₃(CH₂NCH₂C₆H₅)OP(CH(CH₃)2)2)Ni(LiBr)

: 7732-18-5
water

: 1233486-86-6
(κP,κC,κN-2,6-(i-Pr2PO)-C6H3-(N-(benzylamino)methyl))NiBr

Guidance literature:: In toluene; byproducts: LiOH; under N2; Ni complex obtained in situ in toluene soln. reacted with H2O at oom temp.;
DOI:10.1021/ic100914x