tetradec-3-en-1-yne

Base Information

• Chemical Name: tetradec-3-en-1-yne
• CAS No.: 92431-79-3
• Molecular Formula: C₁₄H₂₄
• Molecular Weight: 192.345
• Mol file: 92431-79-3.mol

Synonyms:tetradec-3-en-1-yne

Chemical Property of tetradec-3-en-1-yne

Chemical Property:

Purity/Quality:

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• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of tetradec-3-en-1-yne

There total 1 articles about tetradec-3-en-1-yne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

(±)-tetradec-1-yn-3-ol (73501-38-9,77889-04-4,136022-04-3) → 1-tetradecyne (765-10-6) + tetradec-3-en-1-yne (92431-79-3)

Guidance literature:

With ammonium tetrafluoroborate; [(η5-C5Me5)ruthenium(III)Cl(μ2-SMe)2ruthenium(III)Cl(η5-C5Me5)]; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; In tetrahydrofuran; at 60 ℃; for 6h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.0c00187

Reference yield: 70.0%

tetradec-3-en-1-yne (92431-79-3) + carbon monoxide (201230-82-2) → pentadeca-2,4-dienal (85769-29-5)

Guidance literature:

With dicarbonyl(acetylacotonato)rhodium(I); hydrogen; 2,2'-bis((bis(5-methoxy-1H-indol-1-yl)phosphaneyl)oxy)-1,1'-biphenyl; In toluene; at 25 ℃; for 8h; under 7500.75 Torr; Autoclave;

DOI:10.1021/acs.orglett.1c02140

upstream raw materials:

(±)-tetradec-1-yn-3-ol

Downstream raw materials:

pentadeca-2,4-dienal