1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene

Base Information

• Chemical Name: 1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene
• CAS No.: 1228177-62-5
• Molecular Formula: C₄₄H₄₄Br₂N₄O₂
• Molecular Weight: 820.667
• Mol file: 1228177-62-5.mol

Synonyms:1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene

Chemical Property of 1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene

There total 1 articles about 1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

pyrrole (109-97-7,30604-81-0) + 6,6'-(4,4'-(1,4-phenylene)bis(butane-4,1-diyl))bis(oxy)bis(3-bromobenzaldehyde) (1228177-61-4) → 1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene (1228177-62-5)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 0 ℃; Inert atmosphere;

DOI:10.1021/jo100434t

Reference yield: 27.0%

1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene (1228177-62-5) + benzaldehyde (100-52-7) → C58H46Br2N4O2 + C58H44Br2N4O2Zn (1228177-59-0)

Guidance literature:

1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene; benzaldehyde; With zinc(II) acetate dihydrate; propionic acid; trifluoroacetic acid; In dichloromethane; at 0 ℃; Inert atmosphere; Reflux;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; for 6h;

DOI:10.1021/jo100434t

Reference yield: 22.0%

1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene (1228177-62-5) + benzaldehyde (100-52-7) → C58H46Br2N4O2

Guidance literature:

1,4-bis(4-(4-bromo-2-(di(1H-pyrrol-2-yl)methyl)phenoxy)butyl)-benzene; benzaldehyde; With propionic acid; trifluoroacetic acid; In dichloromethane; at 0 ℃; Inert atmosphere; Reflux;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; for 6h;

DOI:10.1021/jo100434t

upstream raw materials:

pyrrole

6,6'-(4,4'-(1,4-phenylene)bis(butane-4,1-diyl))bis(oxy)bis(3-bromobenzaldehyde)

Downstream raw materials:

C₅₈H₄₄Br₂N₄O₂Zn