tert-butyl[(1R)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl]oxydiphenylsilane

Base Information

Chemical Name:tert-butyl[(1R)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl]oxydiphenylsilane
CAS No.:1333419-90-1
Molecular Formula:C₃₂H₄₈O₃Si
Molecular Weight:508.817
Hs Code.:

Synonyms:tert-butyl[(1R)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl]oxydiphenylsilane

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Chemical Property of tert-butyl[(1R)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl]oxydiphenylsilane

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Technology Process of tert-butyl[(1R)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl]oxydiphenylsilane

There total 9 articles about tert-butyl[(1R)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl]oxydiphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 110-87-2
3,4-dihydro-2H-pyran

: 1333419-89-8
(10R)-10-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-1-undecen-6-ol

: 1333419-90-1
tert-butyl[(1R)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl]oxydiphenylsilane

Guidance literature:: With pyridinium p-toluenesulfonate; In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1055/s-0030-1260058

Reference yield:

: 855256-87-0
(5R)-5-[1-(tert-butyl)-1,1-diphenylsilyl]oxyhexanal

: 1333419-90-1
tert-butyl[(1R)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl]oxydiphenylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: magnesium / tetrahydrofuran / 0.5 h / 20 - 25 °C / Inert atmosphere

1.2: 1 h / Inert atmosphere

2.1: pyridinium p-toluenesulfonate / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

With pyridinium p-toluenesulfonate; magnesium; In tetrahydrofuran; dichloromethane; 1.2: Grignard reaction;
DOI:10.1055/s-0030-1260058

Reference yield:

: 929626-53-9
(2S)-2-[4-(2-oxiranyl)butoxy]tetrahydro-2H-pyran

: 1333419-90-1
tert-butyl[(1R)-1-methyl-5-(tetrahydro-2H-2-pyranyloxy)-9-decenyl]oxydiphenylsilane

Guidance literature:: Multi-step reaction with 6 steps

1.1: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / 0 - 20 °C / Inert atmosphere

2.1: 1H-imidazole; dmap / dichloromethane / 4 h / 0 - 25 °C / Inert atmosphere

3.1: pyridinium p-toluenesulfonate / ethanol / 1 h / 60 °C

4.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dichloromethane; dimethyl sulfoxide / 0.5 h / 20 °C / Inert atmosphere

5.1: magnesium / tetrahydrofuran / 0.5 h / 20 - 25 °C / Inert atmosphere

5.2: 1 h / Inert atmosphere

6.1: pyridinium p-toluenesulfonate / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

With 1H-imidazole; dmap; lithium aluminium tetrahydride; pyridinium p-toluenesulfonate; magnesium; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; ethanol; dichloromethane; dimethyl sulfoxide; 5.2: Grignard reaction;
DOI:10.1055/s-0030-1260058