tetracarbonyl(η-styrene)iron

Base Information

• Chemical Name: tetracarbonyl(η-styrene)iron
• CAS No.: 12193-57-6
• Molecular Formula: C₁₂H₈FeO₄
• Molecular Weight: 272.04
• Mol file: 12193-57-6.mol

Synonyms:tetracarbonyl(η-styrene)iron

Chemical Property of tetracarbonyl(η-styrene)iron

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of tetracarbonyl(η-styrene)iron

There total 3 articles about tetracarbonyl(η-styrene)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + diiron nonacarbonyl (15321-51-4) → tetracarbonyl(η-styrene)iron (12193-57-6)

Guidance literature:

In further solvent(s); under Ar, styrene as solvent and Fe2(CO)9 stirred in pentane at 20°C for 2 d;

DOI:10.1016/S0022-328X(00)85703-4

Reference yield: 64.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + diiron nonacarbonyl (15321-51-4) → iron pentacarbonyl (13463-40-6,37220-42-1) + triiron dodecarbonyl (17685-52-8) + tetracarbonyl(η-styrene)iron (12193-57-6)

Guidance literature:

In pentane; under Ar, equimolar amts. of styrene and Fe2(CO)9 stirred in pentane at20°C for 2-3 d; filtered, evapd. at 20°C/1 Torr, chromd. (neutral Al2O3 (activity I), pentane, at 5°C), concd., styrene sepd. by short-path distn. (20°C; 0.001 Torr), crystals purified by crystn. from pentane at -80°C;

DOI:10.1016/S0022-328X(00)85703-4

Reference yield: 63.0%

bis(triphenylphosphine)iminium tetracarbonyl(E-2-phenylvinyl)ferrate + trifluoroacetic acid (76-05-1) → tetracarbonyl(η-styrene)iron (12193-57-6)

Guidance literature:

In dichloromethane; Ar-atmosphere; equimolar amts., room temp., 10 min; distn. of solvent, extn. (light petroleum), evapn.;

DOI:10.1039/DT9790000395

upstream raw materials:

trifluoroacetic acid

styrene

diiron nonacarbonyl

Downstream raw materials:

triiron dodecarbonyl

Fe(CO)4(Sb(C₆H₅)3)

Refernces