Technology Process of C5H5FeCO{P(OC6H5)3}{CHCH2}
There total 4 articles about C5H5FeCO{P(OC6H5)3}{CHCH2} which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
silver tetrafluoroborate;
In
tetrahydrofuran;
(N2); (1) Fe complex and AgBF4 stirred in CH2Cl2 at room temp. for 10 min, CH3C2CH3 added, stirred for 30 min, filtered (Celite), evapd., (2) dissolved in THF at -78°C, mixed with (CH2CH)2Cu(CN)Li2 (made from CH2CHLi and CuCN in THF),; reacted for 5 min, warmed slowly to room temp.; evapd., redissolved in C6H6, chromd. (Al2O3, pentane, then C6H6/pentane); elem. anal.;
- Guidance literature:
-
With
silver tetrafluoroborate;
In
tetrahydrofuran;
(N2); (1) Fe complex and AgBF4 stirred in THF at room temp. for 30 min, filtered (Celite), cooled to -78°C, mixed with (CH2CH)2Cu(CN)Li2 (made from CH2CHLi and CuCN in THF at -78°C), allowed to warm to room temp.; filtered (Celite), evapd., redissolved in C6H6, chromd. (Al2O3, pentane, then C6H6/pentane), evapd.; elem. anal.;
