N-benzyl-O-(tert-butyldimethylsilyl)-N-[(S)-(3,4-dihydro-2H-pyran-6-yl)((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl]hydroxylamine

Base Information

Chemical Name:N-benzyl-O-(tert-butyldimethylsilyl)-N-[(S)-(3,4-dihydro-2H-pyran-6-yl)((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl]hydroxylamine
CAS No.:1198077-69-8
Molecular Formula:C₂₄H₃₉NO₄Si
Molecular Weight:433.663
Hs Code.:

Synonyms:N-benzyl-O-(tert-butyldimethylsilyl)-N-[(S)-(3,4-dihydro-2H-pyran-6-yl)((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl]hydroxylamine

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Chemical Property of N-benzyl-O-(tert-butyldimethylsilyl)-N-[(S)-(3,4-dihydro-2H-pyran-6-yl)((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl]hydroxylamine

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Technology Process of N-benzyl-O-(tert-butyldimethylsilyl)-N-[(S)-(3,4-dihydro-2H-pyran-6-yl)((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl]hydroxylamine

There total 3 articles about N-benzyl-O-(tert-butyldimethylsilyl)-N-[(S)-(3,4-dihydro-2H-pyran-6-yl)((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl]hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 110-87-2
3,4-dihydro-2H-pyran

: 69739-34-0
t-butyldimethylsiyl triflate

: 91190-38-4,111058-38-9,1165677-00-8
N-benzyl-1,2-O-isopropylidene-D-glyceraldehyde nitrone

: 1198077-69-8
N-benzyl-O-(tert-butyldimethylsilyl)-N-[(S)-(3,4-dihydro-2H-pyran-6-yl)((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl]hydroxylamine

: 1198077-68-7
N-benzyl-O-(tert-butyldimethylsilyl)-N-[(R)-(3,4-dihydro-2H-pyran-6-yl)((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl]hydroxylamine

Guidance literature:: 3,4-dihydro-2H-pyran; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 - 0 ℃; for 4h; Inert atmosphere;

N-benzyl-1,2-O-isopropylidene-D-glyceraldehyde nitrone; With diethylaluminium chloride; In tetrahydrofuran; hexane; pentane; at -78 ℃; for 0.583333h; Inert atmosphere;

t-butyldimethylsiyl triflate; With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.3762/bjoc.6.75

Reference yield: 44.0%

: 110-87-2
3,4-dihydro-2H-pyran

: 69739-34-0
t-butyldimethylsiyl triflate

: 91190-38-4,111058-38-9,1165677-00-8
N-benzyl-1,2-O-isopropylidene-D-glyceraldehyde nitrone

: 1198077-51-8
N-benzyl-O-(tert-butyldimethylsilyl)-N-((R)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-ethoxyallyl)hydroxylamine

: 1198077-69-8
N-benzyl-O-(tert-butyldimethylsilyl)-N-[(S)-(3,4-dihydro-2H-pyran-6-yl)((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl]hydroxylamine

Guidance literature:: 3,4-dihydro-2H-pyran; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 - 0 ℃; for 2h; Inert atmosphere;

N-benzyl-1,2-O-isopropylidene-D-glyceraldehyde nitrone; In tetrahydrofuran; pentane; at -78 ℃; for 1.25h;

t-butyldimethylsiyl triflate; With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.3762/bjoc.6.75