2-(3,7-dimethylocta-1,6-dien-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-(3,7-dimethylocta-1,6-dien-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:1174918-99-0
Molecular Formula:C₁₆H₂₉BO₂
Molecular Weight:264.216
Hs Code.:

Synonyms:2-(3,7-dimethylocta-1,6-dien-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Chemical Property of 2-(3,7-dimethylocta-1,6-dien-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Technology Process of 2-(3,7-dimethylocta-1,6-dien-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 2 articles about 2-(3,7-dimethylocta-1,6-dien-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 5389-87-7
1-chloro-3,7-dimethylocta-2,6-diene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1174918-99-0
2-(3,7-dimethylocta-1,6-dien-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With magnesium; In tetrahydrofuran; at 20 ℃; for 4h; Inert atmosphere;
DOI:10.1021/ja502280w

Reference yield:

: 5389-87-7
1-chloro-3,7-dimethylocta-2,6-diene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1174918-99-0
2-(3,7-dimethylocta-1,6-dien-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1057662-85-7
2-(3,7-dimethylocta-2,6-dienyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With bis(trifluoromethane)sulfonimide lithium; In tetrahydrofuran; byproducts: HCl; Electrolysis; geranyl chloride (1 mmol) and pinacolborane (3 mmol) added to THF containing 0.7 M (CF3SO2)2NLi under N2; electrolyzed with Al anode and Ni cathode (room temp., const. c.d. of 0.15 A/dm2) to 2-3 F/mol; evapd. (vac.); hydrolyzed with H2O; extd. with Et2O; org. phase washed with H2O and satd. aq. NaCl; dried over MgSO4; concd. (vac.); pyrified bycolumn chromy. (silica-gel, petroleum ether-Et2O);
DOI:10.1016/j.electacta.2009.01.015

Reference yield:

: 21087-29-6
trans-3-phenylprop-2-enyl chloride

: 1174918-99-0
2-(3,7-dimethylocta-1,6-dien-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: ((3R,4R)-4,8-dimethyl-4-vinylnona-1,7-dien-3-yl)benzene

: (4,8-dimethyl-4-vinylnona-1,7-dien-3-yl)benzene

Guidance literature:: With [(R)-(+)-2,2'-bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl]palladium(II) dichloride; cesium fluoride; In tetrahydrofuran; at 20 ℃; for 14h; Overall yield = 92 %; Overall yield = 46.7 mg; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja502280w