(2E,4E,6E,8E,10E)-13-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-2,7,11-trimethyl-trideca-2,4,6,8,10-pentaen-12-ynal

Base Information

Chemical Name:(2E,4E,6E,8E,10E)-13-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-2,7,11-trimethyl-trideca-2,4,6,8,10-pentaen-12-ynal
CAS No.:162302-59-2
Molecular Formula:C₂₅H₃₂O₂
Molecular Weight:364.528
Hs Code.:

Synonyms:(2E,4E,6E,8E,10E)-13-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-2,7,11-trimethyl-trideca-2,4,6,8,10-pentaen-12-ynal

Suppliers and Price of (2E,4E,6E,8E,10E)-13-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-2,7,11-trimethyl-trideca-2,4,6,8,10-pentaen-12-ynal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2E,4E,6E,8E,10E)-13-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-2,7,11-trimethyl-trideca-2,4,6,8,10-pentaen-12-ynal

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (2E,4E,6E,8E,10E)-13-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-2,7,11-trimethyl-trideca-2,4,6,8,10-pentaen-12-ynal

There total 7 articles about (2E,4E,6E,8E,10E)-13-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-2,7,11-trimethyl-trideca-2,4,6,8,10-pentaen-12-ynal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: (R)-4-((3E,5E,7E,9E,11E)-13,13-Dimethoxy-3,7,12-trimethyl-trideca-3,5,7,9,11-pentaen-1-ynyl)-3,5,5-trimethyl-cyclohex-3-enol

: 162302-59-2
(2E,4E,6E,8E,10E)-13-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-2,7,11-trimethyl-trideca-2,4,6,8,10-pentaen-12-ynal

Guidance literature:: With water; acetic acid; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.3891/acta.chem.scand.51-1096

Reference yield:

: (all-E)-(7-formyl-2-methyl-2,4,6-octatrienyl)triphenylphosphonium bromide

: 159171-18-3
2-E-5-((4'R)-4'-hydroxy-2',2',6'-trimethylcyclohex-1'-enyl)-3-methyl-2-penten-4-yn-1-al

: 162302-59-2
(2E,4E,6E,8E,10E)-13-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-2,7,11-trimethyl-trideca-2,4,6,8,10-pentaen-12-ynal

Guidance literature:: With sodium hydride; In dichloromethane; at 20 ℃; for 40h; Yield given;

Reference yield:

: ((2E,4E,6E)-8,8-Dimethoxy-2,7-dimethyl-octa-2,4,6-trienyl)-triphenyl-phosphonium; bromide

: 162302-59-2
(2E,4E,6E,8E,10E)-13-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-2,7,11-trimethyl-trideca-2,4,6,8,10-pentaen-12-ynal

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydride / CH₂Cl₂ / 17 h / 20 °C

2: 85 percent / acetic acid, water / CH₂Cl₂ / 0.5 h / 0 °C

With water; sodium hydride; acetic acid; In dichloromethane;
DOI:10.3891/acta.chem.scand.51-1096