Technology Process of cis-[Re(CO)4I(PPh3)]
There total 10 articles about cis-[Re(CO)4I(PPh3)] which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
triphenylphosphine;
palladium(II) oxide;
In
benzene;
byproducts: CO; (N2); heated to 43°C; 31 min; monitored by TLC ( silica plates; hexane/benzene ) and IR; filtered through cellulose and pumped to dryness; removal of the solvent; elem. anal.;
DOI:10.1016/0022-328X(91)86314-G
- Guidance literature:
-
In
1,3,5-trimethyl-benzene;
byproducts: CO; under Ar, molar educt ratio GaI3 : Re-compound = 1:2, refluxing for 24 h; filtration, reduction of volume, washed with n-pentane; elem. anal.;
- Guidance literature:
-
With
iodine;
In
dichloromethane;
under N2; slow addn. of soln. of I2 to soln. of complex; addn. of aq. Na2S2O3 soln. after 30 min, organic layer separated, dried (MgSO4), filtered (Celite), evapd. (vac.), trans-product isolated by fractional crystn. (hexane), cis-product by column chromy. (silica gel, benzene/hexane); elem. anal.;
