2-benzyl-1-bromonaphthalene

Base Information

• Chemical Name: 2-benzyl-1-bromonaphthalene
• CAS No.: 108978-33-2
• Molecular Formula: C₁₇H₁₃Br
• Molecular Weight: 297.194
• Mol file: 108978-33-2.mol

Synonyms:2-benzyl-1-bromonaphthalene

Chemical Property of 2-benzyl-1-bromonaphthalene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-benzyl-1-bromonaphthalene

There total 5 articles about 2-benzyl-1-bromonaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

1-bromo-2-(bromomethyl)naphthalene (37763-43-2) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 2-benzyl-1-bromonaphthalene (108978-33-2)

Guidance literature:

With aluminum (III) chloride; In nitrobenzene; at 20 - 100 ℃; for 4h; Inert atmosphere;

DOI:10.1021/jacs.7b07519

Reference yield:

1-bromo-2-methylnaphtalene (2586-62-1) → 2-benzyl-1-bromonaphthalene (108978-33-2)

Guidance literature:

Multi-step reaction with 2 steps

1: dibenzoyl peroxide; N-Bromosuccinimide / tetrachloromethane / 6 h / Inert atmosphere; Reflux

2: aluminum (III) chloride / nitrobenzene / 4 h / 20 - 100 °C / Inert atmosphere

With aluminum (III) chloride; N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane; nitrobenzene; 2: |Friedel-Crafts Alkylation;

DOI:10.1021/jacs.7b07519

Reference yield:

1-bromo-2-naphthaldehyde (3378-82-3) → 2-benzyl-1-bromonaphthalene (108978-33-2)

Guidance literature:

With diethyl ether; phenylmagnesium bromide; benzene; Erhitzen des Reaktionsprodukts in Essigsaeure mit Jod und rotem Phosphor;

DOI:10.1039/jr9570002790

upstream raw materials:

1-bromo-2-naphthaldehyde

1-bromo-2-(bromomethyl)naphthalene

benzene

1-bromo-2-methylnaphtalene