benzyl ((S)-5-methyl-2-((S)-2-methyloxiran-2-yl)hex-1-en-3-yl)carbamate

Base Information

Chemical Name:benzyl ((S)-5-methyl-2-((S)-2-methyloxiran-2-yl)hex-1-en-3-yl)carbamate
CAS No.:1619233-29-2
Molecular Formula:C₁₈H₂₅NO₃
Molecular Weight:303.401
Hs Code.:

Synonyms:benzyl ((S)-5-methyl-2-((S)-2-methyloxiran-2-yl)hex-1-en-3-yl)carbamate

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Chemical Property of benzyl ((S)-5-methyl-2-((S)-2-methyloxiran-2-yl)hex-1-en-3-yl)carbamate

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Technology Process of benzyl ((S)-5-methyl-2-((S)-2-methyloxiran-2-yl)hex-1-en-3-yl)carbamate

There total 1 articles about benzyl ((S)-5-methyl-2-((S)-2-methyloxiran-2-yl)hex-1-en-3-yl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: benzyl ((S)-4-methyl-1-((R)-2-methyloxiran-2-yl)-1-oxopentan-2-yl)carbamate

: 1779-49-3
Methyltriphenylphosphonium bromide

: 1619233-29-2
benzyl ((S)-5-methyl-2-((S)-2-methyloxiran-2-yl)hex-1-en-3-yl)carbamate

Guidance literature:: Methyltriphenylphosphonium bromide; With potassium hexamethylsilazane; In tetrahydrofuran; toluene; at 20 ℃; for 1h; Inert atmosphere;

benzyl ((S)-4-methyl-1-((R)-2-methyloxiran-2-yl)-1-oxopentan-2-yl)carbamate; In tetrahydrofuran; toluene; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1039/c4ob00893f

Reference yield: 39.0%

: 1619233-29-2
benzyl ((S)-5-methyl-2-((S)-2-methyloxiran-2-yl)hex-1-en-3-yl)carbamate

: 1619233-30-5
benzyl ((S)-3-methyl-1-((2R, 2'R)-2'-methyl-[2,2'-bioxiran]-2-yl)butyl)carbamate

: 1619233-39-4
benzyl ((S)-3-methyl-1-((2S, 2'R)-2'-methyl-[2,2'-bioxiran]-2-yl)butyl)carbamate

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; Inert atmosphere;
DOI:10.1039/c4ob00893f

Reference yield:

: 1619233-29-2
benzyl ((S)-5-methyl-2-((S)-2-methyloxiran-2-yl)hex-1-en-3-yl)carbamate

: 1619233-19-0
benzyl ((S)-4-methyl-1-(((S)-4-methyl-1-(((S)-3-methyl-1-((2R, 2'R)-2'-methyl-[2,2'-bioxiran]-2-yl)butyl)amino)-1-oxopentan-2-yl)amino)-1-oxopentan-2-yl)carbamate

Guidance literature:: Multi-step reaction with 3 steps

1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 20 °C / Inert atmosphere

2.1: palladium 10% on activated carbon; cyclohexa-1,4-diene / methanol; tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

3.1: tert.-butylnitrite; hydrogenchloride / dichloromethane; N,N-dimethyl-formamide; 1,4-dioxane / 3 h / -30 °C / Inert atmosphere

3.2: 20 °C / Inert atmosphere

With hydrogenchloride; tert.-butylnitrite; cyclohexa-1,4-diene; palladium 10% on activated carbon; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/c4ob00893f