3,10-bis(2-nitrobenzenesulfonyl)-6-(1-pyrenebutyryl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1⁽¹⁶⁾,12,14-triene

Base Information

• Chemical Name: 3,10-bis(2-nitrobenzenesulfonyl)-6-(1-pyrenebutyryl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1⁽¹⁶⁾,12,14-triene
• CAS No.: 221297-56-9
• Molecular Formula: C₄₄H₄₀N₆O₉S₂
• Molecular Weight: 860.968

Synonyms:3,10-bis(2-nitrobenzenesulfonyl)-6-(1-pyrenebutyryl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1⁽¹⁶⁾,12,14-triene

Chemical Property of 3,10-bis(2-nitrobenzenesulfonyl)-6-(1-pyrenebutyryl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1⁽¹⁶⁾,12,14-triene

Chemical Property:

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Technology Process of 3,10-bis(2-nitrobenzenesulfonyl)-6-(1-pyrenebutyryl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1⁽¹⁶⁾,12,14-triene

There total 3 articles about 3,10-bis(2-nitrobenzenesulfonyl)-6-(1-pyrenebutyryl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1⁽¹⁶⁾,12,14-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1-pyrenebutyric acid (3443-45-6) + 3,10-bis(2-nitrobenzenesulfonyl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1(16),12,14-triene (221297-42-3) → 3,10-bis(2-nitrobenzenesulfonyl)-6-(1-pyrenebutyryl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1(16),12,14-triene (221297-56-9)

Guidance literature:

With 4-methyl-morpholine; benzotriazol-1-ol; dicyclohexyl-carbodiimide; In N,N-dimethyl-formamide; acetonitrile; at 20 ℃; for 40h;

DOI:10.1002/jhet.5570370403

Reference yield:

1,3-Dicyclohexylcarbodiimide (DCC) + 1-pyrenebutyric acid (3443-45-6) + benzotriazol-1-ol (2592-95-2) + 3,10-bis(2-nitrobenzenesulfonyl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1(16),12,14-triene (221297-42-3) → 3,10-bis(2-nitrobenzenesulfonyl)-6-(1-pyrenebutyryl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1(16),12,14-triene (221297-56-9)

Guidance literature:

With 4-methyl-morpholine; In dichloromethane;

Reference yield:

3,10-Bis-(2-nitro-benzenesulfonyl)-3,6,10,16-tetraaza-bicyclo[10.3.1]hexadeca-1(16),12,14-triene-6-carboxylic acid tert-butyl ester (182576-27-8) → 3,10-bis(2-nitrobenzenesulfonyl)-6-(1-pyrenebutyryl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1(16),12,14-triene (221297-56-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 73 percent / TFA / CH₂Cl₂ / 20 °C

2: 92 percent / DCC; HOBT; 4-methylmorpholine / dimethylformamide; acetonitrile / 40 h / 20 °C

With 4-methyl-morpholine; benzotriazol-1-ol; dicyclohexyl-carbodiimide; trifluoroacetic acid; In dichloromethane; N,N-dimethyl-formamide; acetonitrile; 1: acidolysis / 2: Acylation;

DOI:10.1002/jhet.5570370403

upstream raw materials:

1-pyrenebutyric acid

3,10-bis(2-nitrobenzenesulfonyl)-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1⁽¹⁶⁾,12,14-triene

3,10-Bis-(2-nitro-benzenesulfonyl)-3,6,10,16-tetraaza-bicyclo[10.3.1]hexadeca-1⁽¹⁶⁾,12,14-triene-6-carboxylic acid tert-butyl ester

benzotriazol-1-ol

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