Z-Sar-OPfp

Base Information

• Chemical Name: Z-Sar-OPfp
• CAS No.: 80909-58-6
• Molecular Formula: C₁₇H₁₂F₅NO₄
• Molecular Weight: 389.279
• DSSTox Substance ID: DTXSID201139957

Synonyms:Z-Sar-OPfp;80909-58-6;SCHEMBL8571381;BOMDXDLLXBSFDG-UHFFFAOYSA-N;DTXSID201139957;N-Methyl-N-[(phenylmethoxy)carbonyl]glycine 2,3,4,5,6-pentafluorophenyl ester

Chemical Property of Z-Sar-OPfp

Chemical Property:

• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 7
• Exact Mass: 389.06864867
• Heavy Atom Count: 27
• Complexity: 504

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CN(CC(=O)OC1=C(C(=C(C(=C1F)F)F)F)F)C(=O)OCC2=CC=CC=C2

Technology Process of Z-Sar-OPfp

There total 1 articles about Z-Sar-OPfp which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

2,3,4,5,6-pentafluorophenol (771-61-9) + N-(Benzyloxycarbonyl)sarcosine (39608-31-6) → pentafluorophenyl N-((benzyloxy)carbonyl)-N-methylglycinate (80909-58-6)

Guidance literature:

With dicyclohexyl-carbodiimide; In tetrahydrofuran; at 0 ℃; for 1h;

DOI:10.1016/j.chempr.2021.07.005

Reference yield: 88.0%

ethylenediamine (107-15-3,85404-18-8) + pentafluorophenyl N-((benzyloxy)carbonyl)-N-methylglycinate (80909-58-6) → N-benzyloxycarbonylsarcosine aminoethylamide (171290-67-8)

Guidance literature:

In dichloromethane;

Reference yield: 87.0%

pentafluorophenyl N-((benzyloxy)carbonyl)-N-methylglycinate (80909-58-6) + ((S)-5-Amino-5-{2-[2-(benzyloxycarbonyl-methyl-amino)-acetylamino]-ethylcarbamoyl}-pentyl)-carbamic acid 2,2,2-trichloro-ethyl ester; hydrochloride → ((S)-5-[2-(Benzyloxycarbonyl-methyl-amino)-acetylamino]-5-{2-[2-(benzyloxycarbonyl-methyl-amino)-acetylamino]-ethylcarbamoyl}-pentyl)-carbamic acid 2,2,2-trichloro-ethyl ester

Guidance literature:

With dmap; N-ethyl-N,N-diisopropylamine; In dichloromethane; for 96h; Ambient temperature;

DOI:10.1039/c39950001809

upstream raw materials:

2,3,4,5,6-pentafluorophenol

N-(Benzyloxycarbonyl)sarcosine

Downstream raw materials:

Z-Sar-Arg(NO₂)-Val-Tyr(Bzl)-Cpg-His(Dnp)-Pro-Lac-OBzl

Z-Sar-Arg(NO₂)-Val-Tyr(Bzl)-Chg-His(Dnp)-Pro-Lac-OBzl

Z-Sar-Arg(NO₂)-Val-Tyr(Bzl)-Cpg-His(Dnp)-Pro-Ala-ONB

Z-Sar-Arg(NO₂)-Val-Tyr(Bzl)-Chg-His(Dnp)-Pro-Ala-ONB

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