[(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

Base Information

Chemical Name:[(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]
CAS No.:431882-20-1
Molecular Formula:C₃₂H₁₂BF₂₄*C₃₉H₄₆NOPRhSi
Molecular Weight:1569.99
Hs Code.:

[(C<sub>5</sub>(CH<sub>3</sub>)5)(P(CH<sub>3</sub>)3)Rh((4-methoxy)C<sub>6</sub>H<sub>4</sub>)(CNSi(C<sub>6</sub>H<sub>5</sub>)3)][B(3,5-C<sub>6</sub>H<sub>3</sub>(CF<sub>3</sub>)2)4]

Synonyms:[(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

Suppliers and Price of [(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

There total 3 articles about [(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 431882-00-7
[(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

: 874-90-8
4-methoxybenzonitrile

: 789-25-3
HSiPh₃

: 431882-20-1
[(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

Guidance literature:: In dichloromethane; byproducts: CH4; at 25°C Rh complex was reacted with (C6H5)3SiH for a few s, then with the nitrile for 4 h; the η1-nitrile complex was generated at -40°C, warming to 15°C for 20 min leads to η2-iminoacyl complex and the isonitrile complex; the transient intermediate species was detected by NMR;
DOI:10.1021/ja0255094

Reference yield: 30.0%

: 431882-32-5
[(C5(CH3)5)(P(CH3)3)Rh(Si(C6H5)3)(η1-NC(4-methoxy)C6H4)][B(3,5-C6H3(CF3)2)4]

: 431882-20-1
[(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

: 431882-35-8
[Cp*(PMe3)Rh(η2-C(4-(OMe)C6H4)=N(SiPh3))]B(3,5-C6H3(CF3)2)4

Guidance literature:: In dichloromethane-d2; (inert atm.); warming a soln. of rhodium complex in CD2Cl2 to 15°C for 20 min; layering with pentane, keeping at -30°C for 4 wk;
DOI:10.1021/ja034468o

Reference yield:

: 431882-02-9
[(C₅(CH₃)5)(P(CH₃)3)Rh(Si(C₆H₅)3)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4]

: 874-90-8
4-methoxybenzonitrile

: 431882-20-1
[(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4]

Guidance literature:: In dichloromethane-d2; (inert atm.); addn. of a soln. of nitrile in CD2Cl2 to a soln. of rhodium complex in CD2Cl2 in an NMR tube at -78°C, warming to 0°C; not isolated, detected by NMR; Kinetics;
DOI:10.1021/ja034468o