431882-02-9

Upstream product

• 431882-00-7 [(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(dichloromethane)][B(3,5-C₆H₃(CF₃)2)4] 
• 789-25-3 HSiPh₃ 

Downstream Products

• 431882-17-6 [(C₅(CH₃)5)(P(CH₃)3)Rh((4-trifluoromethyl)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4] 
• 431882-23-4 [(C₅(CH₃)5)(P(CH₃)3)Rh(CH(CH₃)2)(CNSi(C₆H₅)3)]B(3,5-C₆H₃(CF₃)2)4 
• 431882-26-7 [(C5(CH3)5)(P(CH3)3)Rh(Si(C6H5)3)(η1-NCC(CH3)3)][B(3,5-C6H3(CF3)2)4] 
• 431882-29-0 [(C₅(CH₃)5)(P(CH₃)3)Rh(C(CH₃)3)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4] 
• 431882-14-3 [(C₅(CH₃)5)(P(CH₃)3)Rh(C₆H₅)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4] 
• 431882-32-5 [(C5(CH3)5)(P(CH3)3)Rh(Si(C6H5)3)(η1-NC(4-methoxy)C6H4)][B(3,5-C6H3(CF3)2)4] 
• 431882-20-1 [(C₅(CH₃)5)(P(CH₃)3)Rh((4-methoxy)C₆H₄)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4] 
• 431882-11-0 [(C₅(CH₃)5)(P(CH₃)3)Rh(CH₃)(CNSi(C₆H₅)3)][B(3,5-C₆H₃(CF₃)2)4] 
• 431882-05-2 [(C5(CH3)5)(P(CH3)3)Rh(Si(C6H5)3)(η1-NCCH3)][B(3,5-C6H3(CF3)2)4] 

Relevant academic research and scientific papers

Carbon-carbon bond activation of R-CN (R = ME, Ar, iPr, tBu) using a cationic Rh(III) complex

Addition of 1.0 equiv of Ph3SiH to [Cp*(PMe3)Rh(Me)(CH2Cl2)]+BAr'4- (1) resulted in release of methane and quantitative formation of [Cp*(PMe3)Rh(SiPh3)(CH2