[(η5-cyclopentadienyl)Ru[PhP(CH2CH2PPh2)2]]PF6*0.25dichloromethane

Base Information

Chemical Name:[(η5-cyclopentadienyl)Ru[PhP(CH2CH2PPh2)2]]PF6*0.25dichloromethane
CAS No.:79019-68-4
Molecular Formula:0CH₂Cl₂*C₃₉H₃₈P₃Ru*F₆P
Molecular Weight:866.919
Hs Code.:

Synonyms:[(η5-cyclopentadienyl)Ru[PhP(CH2CH2PPh2)2]]PF6*0.25dichloromethane

Suppliers and Price of [(η5-cyclopentadienyl)Ru[PhP(CH2CH2PPh2)2]]PF6*0.25dichloromethane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(η5-cyclopentadienyl)Ru[PhP(CH2CH2PPh2)2]]PF6*0.25dichloromethane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(η5-cyclopentadienyl)Ru[PhP(CH2CH2PPh2)2]]PF6*0.25dichloromethane

There total 2 articles about [(η5-cyclopentadienyl)Ru[PhP(CH2CH2PPh2)2]]PF6*0.25dichloromethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: ammonium hexafluorophosphate

: 32993-05-8
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

: 79019-68-4
[(η5-cyclopentadienyl)Ru[PhP(CH2CH2PPh2)2]]PF6*0.25dichloromethane

Guidance literature:: With dichloromethane; In decalin; under N2, mixt. of educts heated in decalin under reflux for 3 h, cooled; filtered, residue triturated with toluene, dried in vac., stirred with NH4PF6 in wet acetone for 30 min, evapd. in vac., recrystd. from CH2Cl2/Et2O; elem. anal.;

Reference yield:

: ammonium hexafluorophosphate

: 32993-05-8
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

: 23582-02-7
bis(2-diphenylphosphinoethyl)phenylphosphine

: 79019-68-4
((η5-C5H5)Ru[(Ph2PCH2CH2)2PPh])PF6

Guidance literature:: In toluene; refluxed;
DOI:10.1039/c39810000341

Reference yield: 65.0%

: lithium aluminium deuteride

: 79019-68-4
[(η5-cyclopentadienyl)Ru[PhP(CH2CH2PPh2)2]]PF6*0.25dichloromethane

: 84174-45-8
C₅H₅⁽²⁾HRu(P(C₆H₅)2CH₂CH₂)2PC₆H₅

Guidance literature:: In tetrahydrofuran; under N2, LiAlD4 added to stirred soln. of Ru complex in THF, stirred at room temp. for 16 h, cooled (0°C), carefully hydrolyzed; evapd. in vac., dry solid extd. with Et2O, concd., cooled (-30°C), crystals washed with ice-cold petroleum ether, dried in vac.;