32993-05-8Relevant articles and documents
A VERSATILE ROUTE TO (η5-C5R5)RuL2X FROM ALLYLMETHYLRUTHENIUM COMPLEXES
Nagashima, Hideo,Yamaguchi, Keitaro,Mukai, Katsunori,Itoh, Kenji
, p. C20 - C22 (1985)
Divalent ruthenium complexes, (η5-C5R5)RuL2X (R=H, CH3; X=Br, Cl), are formed by thermal decomposition of (η5-C5R5)Ru(CH3)X(η3-C3H5) in the presence of several neutral ligands.
A new ruthenium cyclopentadienyl azole compound with activity on tumor cell lines and trypanosomatid parasites
Rodríguez Arce, Esteban,Sarniguet, Cynthia,Moraes, Tania S.,Vieites, Marisol,Tomaz, A. Isabel,Medeiros, Andrea,Comini, Marcelo A.,Varela, Javier,Cerecetto, Hugo,González, Mercedes,Marques, Fernanda,García, M. Helena,Otero, Lucía,Gambino, Dinorah
, p. 2923 - 2937 (2015)
(Chemical Equation Presented). As part of our efforts to develop organometallic ruthenium compounds bearing activity on both trypanosomatid parasites and tumor cells, a new Ru(II)-cyclopentadienyl clotrimazole complex, [RuCp(PPh3)2(C
The Kinatics of the Reaction of with Various Olefins
Alibrandi, Giuseppe,Mann, Brian E.
, p. 951 - 954 (1994)
A detailed kinetic investigation of the reaction of with cycloheptatriene, cyclohepta-1,3-diene, cyclooctatetraene, penta-1,4-diene, cycloocta-1,5-diene and dimethyl maleate, has been carried out spectrophotometrically in CH2Cl2 at 10 deg C.It is shown that the major mechanism is via dissociation of PPh3 to give which then reacts with the olefin.There is also a second mechanism involving direct attack of the olefin on .
Ashok, R. F. N.,Gupta, M.,Arulsamy, K. S.,Agarwala, U. C.
, p. 169 - 180 (1985)
Tandem transfer hydrogenation-epoxidation of ketone substrates catalysed by alkene-tethered Ru(ii)-NHC complexes
Malan, Frederick P.,Singleton, Eric,Van Rooyen, Petrus H.,Landman, Marilé
, p. 8472 - 8481 (2019/06/14)
A series of nine cyclopentadienyl Ru(ii)-NHC complexes (1-9) have been synthesised by systematically varying the ligand and/or ligand substituents: η5-C5H4R′ (R′ = H, Me), EPh3 (E = P, As), NHC (Im, BIm), where NHC = Im(R)(R′) (R, R′ = Me, Bn, 4-NO2Bn, C2H4Ph, C4H7). Each of the Ru(ii)-NHC complexes features an N-alkenyl tether to attain bidentate NHC ligands. All complexes found application as catalysts in the tandem transfer hydrogenation and epoxidation reactions of carbonyl substrates. The catalytic activity of the complexes was shown to be similar, with efficiencies of up to 69% conversion after 18 hours and varying alcohol:epoxide selectivity for a variety of electronically diverse carbonyl substrates. Complex 3, with a nitro-containing substituent on the NHC ligand, was the only complex that showed preference for the alcohol product over the epoxide after 18 hours of reaction time.
Syntheses of transition metal methoxysiloxides
Richers, Casseday P.,Bertke, Jeffery A.,Rauchfuss, Thomas B.
supporting information, p. 8756 - 8762 (2017/07/22)
The paper describes three methods for the preparation of methoxysiloxide complexes, a rare class of complexes of relevance to room temperature vulcanization (RTV) of polysiloxanes. The salt metathesis reaction involves the use of the recently described re
