2,4,6-Trimethylbenzthiohydroximsaeure-S-(1-methylvinyl)ester

Base Information

• Chemical Name: 2,4,6-Trimethylbenzthiohydroximsaeure-S-(1-methylvinyl)ester
• CAS No.: 113475-88-0
• Molecular Formula: C₁₃H₁₇NOS
• Molecular Weight: 235.35
• Mol file: 113475-88-0.mol

Synonyms:2,4,6-Trimethylbenzthiohydroximsaeure-S-(1-methylvinyl)ester

Chemical Property of 2,4,6-Trimethylbenzthiohydroximsaeure-S-(1-methylvinyl)ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 2,4,6-Trimethylbenzthiohydroximsaeure-S-(1-methylvinyl)ester

There total 4 articles about 2,4,6-Trimethylbenzthiohydroximsaeure-S-(1-methylvinyl)ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

2-mercaptopropene (2028-39-9) + mesitylenecarbonitrile oxide (2904-57-6) → 2,4,6-Trimethylbenzthiohydroximsaeure-S-(1-methylvinyl)ester (113475-88-0)

Guidance literature:

With lithium diisopropyl amide;

Reference yield: 65.0%

2,2-dimethyl[1,3]dithiolane-1,1-dioxide (113475-90-4) + mesitylenecarbonitrile oxide (2904-57-6) → 2,4,6-Trimethylbenzthiohydroximsaeure-S-(1-methylvinyl)ester (113475-88-0)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 4h;

Reference yield: 65.0%

2,2-dimethyl[1,3]dithiolane-1,1-dioxide (113475-90-4) + mesitylenecarbonitrile oxide (2904-57-6) → cyanomesitylene (2571-52-0) + 2,4,6-trimethylphenyl isothiocyanate (6095-82-5) + 2,4,6-Trimethylbenzthiohydroximsaeure-S-(1-methylvinyl)ester (113475-88-0)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide; In tetrahydrofuran; at 0 ℃; for 4h; Product distribution; other LDA-conc.; other temp; further 1,3-dithiolan-1,1-dioxide;

upstream raw materials:

2-mercaptopropene

mesitylenecarbonitrile oxide

4.5-cis-Bis-methoxycarbonyl-2.2-dimethyl-1.3-dithiolan

2,2-dimethyl[1,3]dithiolane-1,1-dioxide