C₁₇H₂₇NOS

Base Information

• Chemical Name: C₁₇H₂₇NOS
• CAS No.: 1361202-86-9
• Molecular Formula: C₁₇H₂₇NOS
• Molecular Weight: 293.473
• Mol file: 1361202-86-9.mol

Synonyms:C₁₇H₂₇NOS

Chemical Property of C₁₇H₂₇NOS

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₇H₂₇NOS

There total 3 articles about C₁₇H₂₇NOS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

C16H23NOS + methylmagnesium bromide (75-16-1) → C17H27NOS + C17H27NOS (1361202-86-9)

Guidance literature:

C₁₆H₂₃NOS; methylmagnesium bromide; In dichloromethane; at -50 - 20 ℃; Inert atmosphere;

With water; ammonium chloride; In dichloromethane; Inert atmosphere;

DOI:10.1021/ol3000519

Reference yield:

cis-6-phenylhex-4-enal (41049-27-8,118495-95-7) → C17H27NOS + C17H27NOS (1361202-86-9)

Guidance literature:

Multi-step reaction with 2 steps

1.1: titanium(IV) tetraethanolate / tetrahydrofuran / 20 °C / Inert atmosphere

2.1: dichloromethane / -50 - 20 °C / Inert atmosphere

2.2: Inert atmosphere

With titanium(IV) tetraethanolate; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ol3000519

Reference yield:

cis-6-phenylhex-4-en-1-ol (105337-05-1,136054-69-8,136028-32-5) → C17H27NOS + C17H27NOS (1361202-86-9)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 1-methyl-1H-imidazole; [2,2]bipyridinyl; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen / acetonitrile / 20 °C

2.1: titanium(IV) tetraethanolate / tetrahydrofuran / 20 °C / Inert atmosphere

3.1: dichloromethane / -50 - 20 °C / Inert atmosphere

3.2: Inert atmosphere

With 1-methyl-1H-imidazole; [2,2]bipyridinyl; titanium(IV) tetraethanolate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen; In tetrahydrofuran; dichloromethane; acetonitrile;

DOI:10.1021/ol3000519

upstream raw materials:

methylmagnesium bromide

cis-6-phenylhex-4-enal

cis-6-phenylhex-4-en-1-ol

Refernces