((3,5-t-Bu₂C₆H₃)N=C(Me)C(Me)=N(3,5-t-Bu₂C₆H₃))PtMe₂

Base Information

Chemical Name:((3,5-t-Bu₂C₆H₃)N=C(Me)C(Me)=N(3,5-t-Bu₂C₆H₃))PtMe₂
CAS No.:404373-39-3
Molecular Formula:C₃₄H₅₄N₂Pt
Molecular Weight:685.896
Hs Code.:

((3,5-t-Bu<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)N=C(Me)C(Me)=N(3,5-t-Bu<sub>2</sub>C<sub>6</sub>H<sub>3</sub>))PtMe<sub>2</sub>

Synonyms:((3,5-t-Bu₂C₆H₃)N=C(Me)C(Me)=N(3,5-t-Bu₂C₆H₃))PtMe₂

Suppliers and Price of ((3,5-t-Bu₂C₆H₃)N=C(Me)C(Me)=N(3,5-t-Bu₂C₆H₃))PtMe₂

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ((3,5-t-Bu₂C₆H₃)N=C(Me)C(Me)=N(3,5-t-Bu₂C₆H₃))PtMe₂

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ((3,5-t-Bu₂C₆H₃)N=C(Me)C(Me)=N(3,5-t-Bu₂C₆H₃))PtMe₂

There total 1 articles about ((3,5-t-Bu₂C₆H₃)N=C(Me)C(Me)=N(3,5-t-Bu₂C₆H₃))PtMe₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: bis[dimethyl(μ-dimethylsulfide)platinum(II)]

: 404373-20-2
1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene

: 404373-39-3
((3,5-t-Bu₂C₆H₃)N=C(Me)C(Me)=N(3,5-t-Bu₂C₆H₃))PtMe₂

Guidance literature:: In toluene; ligand and Pt-complex were added to flask, cooled to -78°C, evacuated, toluene was vac. transferred, warmed to room temp., stirred at room temp. for 3 nights under N2; toluene was removed in vacuo, petroleum ether was added, collected, washed with petroleum ether, dried for several h; elem. anal.;
DOI:10.1021/ja011189x

Reference yield: 76.0%

: 350819-30-6
N,N-p-tolyl-2,3-dimethyl-1,4-diazabutadiene

: 404373-39-3
((3,5-t-Bu₂C₆H₃)N=C(Me)C(Me)=N(3,5-t-Bu₂C₆H₃))PtMe₂

: 2417-95-0
p-tolyllithium

: 878663-71-9
[3,5-(t)Bu₂C₆H₃N=C(Me)C(Me)=N-3,5-(t)Bu₂C₆H₃]Pt(Me)(p-Tol)

: [3,5-(t)Bu₂C₆H₃N=C(Me)C(Me)=N-3,5-(t)Bu₂C₆H₃]Pt(p-Tol)2

Guidance literature:: In hexane; under N2; soln. of p-tolyllithium in Me2S/hexane added to soln. of Pt complex in Me2S at -78°C, stirring overnight, addn. of tert-butyl bromide to remove excess of Li reagent, soln. of diimine in CH2Cl2 added,warming to room temp.; evapn. under vac, residue dissolved in CH2Cl2, filtration through Celite, filtrate stirred at room temp. for 4 h, filtration through alumina, filtrate evapd., residue washed with pentane, dried under vac.; elem. anal.;
DOI:10.1021/om050899z

Reference yield:

: tetrafluoroboric acid

: 404373-39-3
((3,5-t-Bu₂C₆H₃)N=C(Me)C(Me)=N(3,5-t-Bu₂C₆H₃))PtMe₂

: 201230-82-2
carbon monoxide

: 404373-66-6
((C₄H₉)2C₆H₃NCCH₃)2Pt(CH₃)(CO)⁽¹⁺⁾*BF₄^(1-)=((C₄H₉)2C₆H₃NCCH₃)2PtCH₃(CO)BF₄

Guidance literature:: In water; to suspn. of Pt-complex in trifluoroethanol was added aq. soln. of HBF4,stirred at room temp. for few min, flask was degassed and filled with 1 atm of CO, stirred under 1 atm of CO for 24 h; solvent was removed at -20°C to 0°C in vacuo, petroleum ether was added, dried for 30 min; elem. anal.;
DOI:10.1021/ja011189x