3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

Base Information

• Chemical Name: 3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal
• CAS No.: 1126991-60-3
• Molecular Formula: C₁₈H₂₇NO₂
• Molecular Weight: 289.418
• Mol file: 1126991-60-3.mol

Synonyms:3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

Chemical Property of 3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

There total 10 articles about 3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

3-phenyl-propionaldehyde (104-53-0) + 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical (2564-83-2,45842-10-2,126517-51-9,25657-03-8,26933-82-4,54637-06-8,64104-42-3) → 3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal (1126991-60-3)

Guidance literature:

With 2,7-difluoro-9-mesityl-10-phenyl-3,6-di(piperazin-1-yl)acridin-10-ium trifluoroacetate; In acetonitrile; for 24h; Reagent/catalyst; Irradiation; Inert atmosphere;

DOI:10.1021/acs.orglett.1c01673

Reference yield: 84.0%

2,2,6,6-tetramethyl-piperidine-N-oxyl (2564-83-2) + 4-(3-phenyl-1-propen-1-yl)-morpholine (39655-59-9) → 3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal (1126991-60-3)

Guidance literature:

With tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; In dichloromethane; acetonitrile; at 20 ℃; for 5h; visible light irradiation; Inert atmosphere;

DOI:10.1246/cl.2009.166

Reference yield: 56.0%

3-phenyl-propionaldehyde (104-53-0) + 2,2,6,6-tetramethyl-piperidine-N-oxyl (2564-83-2) → 3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal (1126991-60-3)

Guidance literature:

With morpholine; tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; In acetonitrile; at 20 ℃; for 24h; visible light irradiation; Inert atmosphere;

DOI:10.1246/cl.2009.166

upstream raw materials:

3-phenyl-propionaldehyde

2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

2,2,6,6-tetramethyl-piperidine-N-oxyl

4-(3-phenyl-1-propen-1-yl)-morpholine

Downstream raw materials:

(S)-3-phenyl-2-(2,2,6,6-tetramethylpiperidin-1-yloxyl)propan-1-ol