(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)S-p-C6H4(methyl)}

Base Information

Chemical Name:(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)S-p-C6H4(methyl)}
CAS No.:111237-19-5
Molecular Formula:C₃₆H₃₅FeO₅PS
Molecular Weight:666.558
Hs Code.:

Synonyms:(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)S-p-C6H4(methyl)}

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Chemical Property of (Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)S-p-C6H4(methyl)}

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Technology Process of (Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)S-p-C6H4(methyl)}

There total 1 articles about (Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)S-p-C6H4(methyl)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 111237-29-7
{(Cp)iron(carbonyl){P(O(phenyl))3}{η2-(methyl)CCCH2O(methyl)}tetrafluoroborate

: 10486-08-5
sodium p-thiocresolate

: 111237-19-5
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)S-p-C6H4(methyl)}

Guidance literature:: In dichloromethane; Dissolving of (CpFeCO(POPh)3)(eta.2-MeCCCH2OMe)(BF4) under N2, cooling (-78°C), addn. to chilled (-78°C) p-NaSC6H4CH3, stirring of mixt. (8 h, -78°C), removing from cold bath, stirring (2 h).; Evapn. of solvent, redissolving of residue in benzene, filtering through Al2O3 (eluants: hexane, benzene), yellow oil results, two rotamers in an approx. ratio of 7:4 are observed by (13)C NMR, elem. anal.;

Reference yield: 73.0%

: 111237-19-5
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)S-p-C6H4(methyl)}

: 102-54-5,55404-68-7
ferrocene

: 111237-22-0
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-COC(CH2O(methyl))C(methyl)SC6H4(methyl)}

Guidance literature:: With CO; In dichloromethane; Cooling (-78°C) of solns. of (CpFeCO(POPh)3)(η1-C(CH2OMe)CMeSC6H4M3) and (Cp2Fe)(BF4), stirring (20 min, CO, 1 atm), addn. of (Cp2Fe)(BF4) in CH2Cl2 to alkenyliron complex by CO-pressure, stirring (45 min), removing from cold bath, stirring.; Filtn. through Al2O3 , evapn., chromy. of oil on Al2O3 (eluants: hexane/CH2Cl2, CH2Cl2) yields ferrocene as first band , (CpFeCO(POPh)3)(η1-C(CH2OMe)C(CH3)S-p-C6H4CH3) and yellow oil, elem. anal.;