(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-COC(CH2O(methyl))C(methyl)SC6H4(methyl)}

Base Information

Chemical Name:(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-COC(CH2O(methyl))C(methyl)SC6H4(methyl)}
CAS No.:111237-22-0
Molecular Formula:C₃₇H₃₅FeO₆PS
Molecular Weight:694.568
Hs Code.:

Synonyms:(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-COC(CH2O(methyl))C(methyl)SC6H4(methyl)}

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Chemical Property of (Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-COC(CH2O(methyl))C(methyl)SC6H4(methyl)}

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Technology Process of (Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-COC(CH2O(methyl))C(methyl)SC6H4(methyl)}

There total 1 articles about (Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-COC(CH2O(methyl))C(methyl)SC6H4(methyl)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 111237-19-5
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)S-p-C6H4(methyl)}

: 102-54-5,55404-68-7
ferrocene

: 111237-22-0
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-COC(CH2O(methyl))C(methyl)SC6H4(methyl)}

Guidance literature:: With CO; In dichloromethane; Cooling (-78°C) of solns. of (CpFeCO(POPh)3)(η1-C(CH2OMe)CMeSC6H4M3) and (Cp2Fe)(BF4), stirring (20 min, CO, 1 atm), addn. of (Cp2Fe)(BF4) in CH2Cl2 to alkenyliron complex by CO-pressure, stirring (45 min), removing from cold bath, stirring.; Filtn. through Al2O3 , evapn., chromy. of oil on Al2O3 (eluants: hexane/CH2Cl2, CH2Cl2) yields ferrocene as first band , (CpFeCO(POPh)3)(η1-C(CH2OMe)C(CH3)S-p-C6H4CH3) and yellow oil, elem. anal.;

Reference yield: 79.0%

: 111237-22-0
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-COC(CH2O(methyl))C(methyl)SC6H4(methyl)}

: 111209-37-1
(E)-(methyl)O₂CC(CH₂O(methyl))C(methyl)SC₆H₄(methyl)

Guidance literature:: With CO; (Cp₂Fe)(BF₄); In methanol; dichloromethane; Dissolving of complex in CH2Cl2 under CO, dissolving of (Cp2Fe)(BF4) in MeOH under CO, cooling (-78°C) of both solns., stirring (10 min), addn. of CH2Cl2 soln. to MeOH soln., stirring (2 h, -78°C), warming to room temp.; Evapn., dissolving in CH2Cl2, filtn. through Al2O3, vol. redn., chromy. (SiO2, pentane/Et2O) yields pale yellow oil, IR, (1)H NMR, MS.;