1-phenylvinyl methanesulfonate

Base Information

• Chemical Name: 1-phenylvinyl methanesulfonate
• CAS No.: 1093253-55-4
• Molecular Formula: C₉H₁₀O₃S
• Molecular Weight: 198.243
• Mol file: 1093253-55-4.mol

Synonyms:1-phenylvinyl methanesulfonate

Chemical Property of 1-phenylvinyl methanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-phenylvinyl methanesulfonate

There total 2 articles about 1-phenylvinyl methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

methanesulfonic acid (75-75-2,98527-29-8) + phenylacetylene (536-74-3) → 1-phenylvinyl methanesulfonate (1093253-55-4)

Guidance literature:

With chloro(1,5-cyclooctadiene)rhodium(I) dimer; triphenylphosphine; In 1,2-dichloro-ethane; at 70 ℃; for 2h; regioselective reaction;

DOI:10.1002/cctc.201300228

Reference yield:

methanesulfonic acid (75-75-2,98527-29-8) + phenylacetylene (536-74-3) → styryl methanesulfonate + 1-phenylvinyl methanesulfonate (1093253-55-4)

Guidance literature:

With phthalimide; triphenylphosphinegold(I) nitrate; In 1,2-dichloro-ethane; at 100 ℃; for 4h; regioselective reaction; Inert atmosphere;

DOI:10.1039/b818863g

Reference yield: 93.0%

1-phenylvinyl methanesulfonate (1093253-55-4) → 2-methylsulfonyl-1-phenylethanone (3708-04-1)

Guidance literature:

With eosin B disodium salt; In dimethyl sulfoxide; at 20 ℃; for 1h; Inert atmosphere; Irradiation; Green chemistry;

DOI:10.1039/c7gc01467h

upstream raw materials:

methanesulfonic acid

phenylacetylene

Downstream raw materials:

Benzoesaeure-methansulfonsaeure-anhydrid

2-methylsulfonyl-1-phenylethanone

Refernces

• 1、 Yang, Yong,Chang, Ji Wong,Rioux, Robert M.. "Structural elucidation of supported Rh complexes derived from RhCl(PPh3)3 immobilized on surface-functionalized SBA-15 and their catalytic performance for C-heteroatom (S, O) bond formation". . p. 43 - 54. Retrieved 2018/07/03.
• 2、 Cui, Dong-Mei,Meng, Qian,Zheng, Jin-Zhou,Zhang, Chen. "Gold-catalyzed addition of sulfonic acids to alkynes to form vinyl sulfonates". supporting information; experimental part. p. 1577 - 1579. Retrieved 2009/09/05.