1-C-(2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hexano-furanosyl)acetone

Base Information

Chemical Name:1-C-(2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hexano-furanosyl)acetone
CAS No.:936112-22-0
Molecular Formula:C₂₃H₂₇NO₆
Molecular Weight:413.47
Hs Code.:

Synonyms:1-C-(2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hexano-furanosyl)acetone

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Chemical Property of 1-C-(2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hexano-furanosyl)acetone

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Technology Process of 1-C-(2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hexano-furanosyl)acetone

There total 5 articles about 1-C-(2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hexano-furanosyl)acetone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 936112-20-8
1-C-allyl 2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hexano-furanoside

: 936112-22-0
1-C-(2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hexano-furanosyl)acetone

Guidance literature:: With jones reagent; mercury(II) diacetate; In water; acetone; at 0 ℃; for 3h;
DOI:10.1021/jo070014o

Reference yield:

: 936112-16-2
1-C-allyl 2,3-di-O-benzyl-5-aldo-α-D-ribofuranoside

: 936112-22-0
1-C-(2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hexano-furanosyl)acetone

Guidance literature:: Multi-step reaction with 4 steps

1: 88 percent / sodium methoxide / methanol / 0 - 20 °C

2: 84 percent / TEA; MeSO₂Cl / CH₂Cl₂ / 0.5 h / 0 °C

3: 87 percent / NaBH₄ / methanol / 1 h / 0 - 20 °C

4: 72 percent / Hg(OAc)2; Jones reagent / acetone; H₂O / 3 h / 0 °C

With sodium tetrahydroborate; jones reagent; TEA; mercury(II) diacetate; sodium methylate; methanesulfonyl chloride; In methanol; dichloromethane; water; acetone; 1: Henry reaction;
DOI:10.1021/jo070014o

Reference yield:

: 936112-19-5
1-C-allyl 2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hex-5-eno-furanoside

: 936112-22-0
1-C-(2,3-di-O-benzyl-6-C-nitro-6-deoxy-α-D-ribo-hexano-furanosyl)acetone

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / NaBH₄ / methanol / 1 h / 0 - 20 °C

2: 72 percent / Hg(OAc)2; Jones reagent / acetone; H₂O / 3 h / 0 °C

With sodium tetrahydroborate; jones reagent; mercury(II) diacetate; In methanol; water; acetone;
DOI:10.1021/jo070014o