octanethioic acid S-(1-methyl-3,3-bis-phenylsulfanyl-propyl) ester

Base Information

• Chemical Name: octanethioic acid S-(1-methyl-3,3-bis-phenylsulfanyl-propyl) ester
• CAS No.: 242483-26-7
• Molecular Formula: C₂₄H₃₂OS₃
• Molecular Weight: 432.715
• Mol file: 242483-26-7.mol

Synonyms:octanethioic acid S-(1-methyl-3,3-bis-phenylsulfanyl-propyl) ester

Chemical Property of octanethioic acid S-(1-methyl-3,3-bis-phenylsulfanyl-propyl) ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of octanethioic acid S-(1-methyl-3,3-bis-phenylsulfanyl-propyl) ester

There total 4 articles about octanethioic acid S-(1-methyl-3,3-bis-phenylsulfanyl-propyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

n-octanoic acid chloride (111-64-8) + 4,4-Bis(phenylthio)-2-butanethiol (242483-19-8) → octanethioic acid S-(1-methyl-3,3-bis-phenylsulfanyl-propyl) ester (242483-26-7)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1055/s-1999-2777

Reference yield:

bis(phenylthio)methane (3561-67-9) → octanethioic acid S-(1-methyl-3,3-bis-phenylsulfanyl-propyl) ester (242483-26-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 85 percent / BuLi / tetrahydrofuran / 0.25 h / 0 °C

2: pyridine / 0 - 20 °C

3: 1.) K⁽¹⁺⁾*t-BuOCHS₂^(1-) / 2.) 70-80 deg C

4: 87 percent / Et₃N / tetrahydrofuran / 0 - 20 °C

With pyridine; n-butyllithium; K⁽¹⁺⁾*t-BuOCHS₂^(1-); triethylamine; In tetrahydrofuran;

DOI:10.1055/s-1999-2777

Reference yield:

4,4-Bis-phenylsulfanyl-butan-2-ol (185559-30-2) → octanethioic acid S-(1-methyl-3,3-bis-phenylsulfanyl-propyl) ester (242483-26-7)

Guidance literature:

Multi-step reaction with 3 steps

1: pyridine / 0 - 20 °C

2: 1.) K⁽¹⁺⁾*t-BuOCHS₂^(1-) / 2.) 70-80 deg C

3: 87 percent / Et₃N / tetrahydrofuran / 0 - 20 °C

With pyridine; K⁽¹⁺⁾*t-BuOCHS₂^(1-); triethylamine; In tetrahydrofuran;

DOI:10.1055/s-1999-2777

upstream raw materials:

n-octanoic acid chloride

4,4-Bis(phenylthio)-2-butanethiol

bis(phenylthio)methane

4,4-Bis-phenylsulfanyl-butan-2-ol