3-{4-[(E)-3-methoxy-3-oxoprop-1-enyl]phenoxy}propyl methacrylate

Base Information

• Chemical Name: 3-{4-[(E)-3-methoxy-3-oxoprop-1-enyl]phenoxy}propyl methacrylate
• CAS No.: 937033-87-9
• Molecular Formula: C₁₇H₂₀O₅
• Molecular Weight: 304.343
• Mol file: 937033-87-9.mol

Synonyms:3-{4-[(E)-3-methoxy-3-oxoprop-1-enyl]phenoxy}propyl methacrylate

Chemical Property of 3-{4-[(E)-3-methoxy-3-oxoprop-1-enyl]phenoxy}propyl methacrylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-{4-[(E)-3-methoxy-3-oxoprop-1-enyl]phenoxy}propyl methacrylate

There total 2 articles about 3-{4-[(E)-3-methoxy-3-oxoprop-1-enyl]phenoxy}propyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.7%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + methyl (2E)-3-[4-(3-hydroxypropoxy)phenyl]prop-2-enoate → 3-{4-[(E)-3-methoxy-3-oxoprop-1-enyl]phenoxy}propyl methacrylate (937033-87-9)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In tetrahydrofuran; at 20 ℃;

DOI:10.1039/b110088m

Reference yield:

methyl 4-hydroxycinnamate (3943-97-3) → 3-{4-[(E)-3-methoxy-3-oxoprop-1-enyl]phenoxy}propyl methacrylate (937033-87-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / K₃CO₃ / dimethylformamide / 12 h / 20 °C

2: 86.7 percent / DMAP; DCC / tetrahydrofuran / 20 °C

With dmap; potassium carbonate; dicyclohexyl-carbodiimide; In tetrahydrofuran; N,N-dimethyl-formamide;

DOI:10.1039/b110088m

upstream raw materials:

poly(methacrylic acid)

methyl 4-hydroxycinnamate