2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranosiduronic acid N-phenylamide

Base Information

• Chemical Name: 2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranosiduronic acid N-phenylamide
• CAS No.: 926641-71-6
• Molecular Formula: C₁₈H₂₀BrNO₈
• Molecular Weight: 458.263
• Mol file: 926641-71-6.mol

Synonyms:2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranosiduronic acid N-phenylamide

Chemical Property of 2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranosiduronic acid N-phenylamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranosiduronic acid N-phenylamide

There total 1 articles about 2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranosiduronic acid N-phenylamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Acetic acid (2S,3S,4S,5R,6S)-4,5,6-triacetoxy-2-phenylcarbamoyl-tetrahydro-pyran-3-yl ester (474426-79-4) → 2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranosiduronic acid N-phenylamide (926641-71-6)

Guidance literature:

With hydrogen bromide; In acetic acid;

DOI:10.1016/j.carres.2006.10.023

Reference yield: 35.0%

2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranosiduronic acid N-phenylamide (926641-71-6) → 2,3,4-tri-O-acetyl-1,6-anhydro-6-Z-phenylimino-β-D-glucopyranose (926641-75-0) + 2,3,4-tri-O-acetyl-D-glucopyranuronic acid phenylamide

Guidance literature:

With silver perchlorate; silver carbonate; In dichloromethane;

DOI:10.1016/j.carres.2006.10.023

Reference yield:

2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranosiduronic acid N-phenylamide (926641-71-6) → 2,3,4-tri-O-acetyl-D-glucopyranuronic acid phenylamide

Guidance literature:

With molecular sieve; silver perchlorate; silver carbonate; In dichloromethane;

DOI:10.1016/j.carres.2006.10.023

upstream raw materials:

Acetic acid (2S,3S,4S,5R,6S)-4,5,6-triacetoxy-2-phenylcarbamoyl-tetrahydro-pyran-3-yl ester

Downstream raw materials:

2,3,4-tri-O-acetyl-1,6-anhydro-6-Z-phenylimino-β-D-glucopyranose

phenyl 2,3,4-tri-O-acetyl-β-D-glucopyranuric acid N-phenylamide