syn-11-((allyloxy)carbonyl)-3-(3-(propyloxy)phenyl)-1,6-methano<10>annulene

Base Information

Chemical Name:syn-11-((allyloxy)carbonyl)-3-(3-(propyloxy)phenyl)-1,6-methano<10>annulene
CAS No.:166804-09-7
Molecular Formula:C₂₄H₂₄O₃
Molecular Weight:360.453
Hs Code.:

Synonyms:syn-11-((allyloxy)carbonyl)-3-(3-(propyloxy)phenyl)-1,6-methano<10>annulene

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Chemical Property of syn-11-((allyloxy)carbonyl)-3-(3-(propyloxy)phenyl)-1,6-methano<10>annulene

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Technology Process of syn-11-((allyloxy)carbonyl)-3-(3-(propyloxy)phenyl)-1,6-methano<10>annulene

There total 4 articles about syn-11-((allyloxy)carbonyl)-3-(3-(propyloxy)phenyl)-1,6-methano<10>annulene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 107-08-4
1-iodo-propane

: 166804-08-6
syn-11-((allyloxy)carbonyl)-3-(3-hydroxyphenyl)-1,6-methano<10>annulene

: 166804-09-7
syn-11-((allyloxy)carbonyl)-3-(3-(propyloxy)phenyl)-1,6-methano<10>annulene

Guidance literature:: With caesium carbonate; In acetonitrile; for 18.5h; Ambient temperature;
DOI:10.1021/ja00102a020

Reference yield:

: 142566-67-4
4-(3-((tert-butyldimethylsilyl)oxy)phenyl)<4.4.1>propella-2,8-diene-11-carboxylic acid

: 166804-09-7
syn-11-((allyloxy)carbonyl)-3-(3-(propyloxy)phenyl)-1,6-methano<10>annulene

Guidance literature:: Multi-step reaction with 4 steps

1: 82 percent / Cs₂CO₃ / acetonitrile / 26 h

2: 62 percent / DDQ / dioxane / a) from 60 deg C to 70 deg C, 41 h, b) reflux, 24 h

3: 97 percent / aq. HBr, KF / dimethylformamide / 45 h

4: 88 percent / Cs₂CO₃ / acetonitrile / 18.5 h / Ambient temperature

With potassium fluoride; hydrogen bromide; caesium carbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,4-dioxane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/ja00102a020

Reference yield:

: 166804-07-5
syn-11-((allyloxy)carbonyl)-3-(3-((tert-butyldimethylsilyl)oxy)phenyl)-1,6-methano<10>annulene

: 166804-09-7
syn-11-((allyloxy)carbonyl)-3-(3-(propyloxy)phenyl)-1,6-methano<10>annulene

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / aq. HBr, KF / dimethylformamide / 45 h

2: 88 percent / Cs₂CO₃ / acetonitrile / 18.5 h / Ambient temperature

With potassium fluoride; hydrogen bromide; caesium carbonate; In N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/ja00102a020