1-Iodopropane

Base Information

• Chemical Name: 1-Iodopropane
• CAS No.: 107-08-4
• Molecular Formula: C3H7I
• Molecular Weight: 169.993
• Hs Code.: 29033080
• European Community (EC) Number: 203-460-2
• UN Number: 2392
• UNII: ND3629KE2K
• DSSTox Substance ID: DTXSID501015653
• Nikkaji Number: J4.051G
• Wikipedia: N-Propyl_iodide
• Wikidata: Q161640
• Mol file: 107-08-4.mol

Synonyms:1-iodo-propane;1-iodopropane;propyl iodide

Chemical Property of 1-Iodopropane

Chemical Property:

• Appearance/Colour: colorless transparent liquid
• Vapor Pressure: 38.2mmHg at 25°C
• Melting Point: -101 °C
• Refractive Index: n20/D 1.504(lit.)
• Boiling Point: 102.9 °C at 760 mmHg
• Flash Point: 44.4 °C
• PSA: 0.00000
• Density: 1.754 g/cm³
• LogP: 1.83140
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 169.95925
• Heavy Atom Count: 4
• Complexity: 7.2
• Transport DOT Label: Flammable Liquid

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn:Harmful
• Statements: R10:; R20:; R36/37/38:
• Safety Statements: S16:; S26:; S36/37:

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Halogenated Aliphatics, Saturated
• Canonical SMILES: CCCI

Technology Process of 1-Iodopropane

There total 54 articles about 1-Iodopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

triphenylpropylplumbane (74086-81-0) → iodobenzene (591-50-4) + 1-iodo-propane (107-08-4) + lead(II) iodide (10101-63-0)

Guidance literature:

With I₂; In chloroform-d1; (N2), stirred, treated with 3 equiv I2 at 0°C; filtered; NMR, iodobenzene : 1-iodopropane = 3:1;

DOI:10.1021/om00054a069

Reference yield: 90.0%

2,7-Di-tert-butyl-10b,10c-dipropyl-10b,10c-dihydro-pyrene (76626-77-2) → 2,7-di-tertbutylpyrene (24300-91-2) + 1-iodo-propane (107-08-4)

Guidance literature:

With iodine; In benzene; for 48h; Heating;

DOI:10.1021/ja00377a027

Reference yield: 81.0%

propan-1-ol (71-23-8) → 1-iodo-propane (107-08-4)

Guidance literature:

With iodine; triphenylphosphine; at 20 ℃; for 0.1h; Ionic liquid;

DOI:10.1080/00304940802711127

upstream raw materials:

propan-1-ol

propene

Dipropyl ether

acetyl iodide

Downstream raw materials:

4-propyl-morpholine

4-s-propylpyridine

2-isopropylpyridine

1-propyl-2-(2-hydroxyethyl)piperidine

Refernces

The reactivity of 2,2'-bipyridine complexes in the electrochemical reduction of organohalides

10.1023/A:1016024531639

The research aimed to investigate the reactivity of nickel(0) complexes coordinated with 2,2'-bipyridine (bpy) in the electrochemical reduction of organic halides. The study focused on understanding the mechanism of the catalytic process and identifying the intermediates formed during the reduction. The researchers used nickel complexes with varying numbers of bpy ligands and different organic halides, including alkyl and aryl halides such as propyl iodide, amyl iodide, phenyl bromide, and mesityl bromide. The experiments involved electrochemical techniques like cyclic voltammetry and preparative electrolysis. The study concluded that nickel(0) complexes with fewer bpy ligands were more reactive in the oxidative addition to organic halides, leading to the formation of σ-organonickel intermediates.