ethyl 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(prop-2-en-1-yl)cyclohexanecarboxylate

Base Information

Chemical Name:ethyl 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(prop-2-en-1-yl)cyclohexanecarboxylate
CAS No.:943515-12-6
Molecular Formula:C₁₈H₃₄O₃Si
Molecular Weight:326.552
Hs Code.:

Synonyms:ethyl 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(prop-2-en-1-yl)cyclohexanecarboxylate

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Chemical Property of ethyl 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(prop-2-en-1-yl)cyclohexanecarboxylate

Chemical Property:

Boiling Point:343.3±35.0 °C(Predicted)
Density:0.93±0.1 g/cm3(Predicted)

Purity/Quality:

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Technology Process of ethyl 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(prop-2-en-1-yl)cyclohexanecarboxylate

There total 3 articles about ethyl 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(prop-2-en-1-yl)cyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 106-95-6
allyl bromide

: 676560-15-9
Ethyl (cis/trans)-4-<(tert-butyldimethylsilyl)oxy>cyclohexanecarboxylate

: 943515-12-6
ethyl 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(prop-2-en-1-yl)cyclohexanecarboxylate

Guidance literature:: Ethyl (cis/trans)-4-<(tert-butyldimethylsilyl)oxy>cyclohexanecarboxylate; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.5h;

allyl bromide; In tetrahydrofuran; at -70 ℃; for 1h;

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 943515-12-6
ethyl 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(prop-2-en-1-yl)cyclohexanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C

2.1: lithium diisopropyl amide / tetrahydrofuran / 0.5 h / -78 °C

2.2: 1 h / -70 °C

With 1H-imidazole; lithium diisopropyl amide; In tetrahydrofuran; N,N-dimethyl-formamide;

Reference yield:

: 3618-04-0,75877-66-6,17159-80-7
4-hydroxycyclohexyl carboxylic acid ethyl ester

: 943515-12-6
ethyl 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(prop-2-en-1-yl)cyclohexanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C

2.1: lithium diisopropyl amide / tetrahydrofuran / 0.5 h / -78 °C

2.2: 1 h / -70 °C

With 1H-imidazole; lithium diisopropyl amide; In tetrahydrofuran; N,N-dimethyl-formamide;